1. 毕业设计(论文)的内容和要求
本论文的内容:
镁基氢化物水解释氢作为一种低成本、安全可控的新型释氢方式,在移动氢源中起着关键作用。镁基氢化物水解释氢动力学性能与诸多因素有关。
本课题采用HCS MM制备镁基氢化物,并利用水解方式释氢,采用正交试验法考察镁的添加量、球磨时间、水解温度等因素对反应动力学性能的影响,并通过微结构分析其中的原因及机理。
2. 参考文献
[1]胡子龙.贮氢材料[M].北京:化学工业出版社,2002. [2]牛娇.制氢技术的系统评价体系研究[D].北京:北京化工大学,2007. [3]夏晓峰,曾如意.生物制氢的发展现状[J].福建轻纺,2005,(7):5~10. [4]V.C.Y..Kong,F.R..Foulkes,D.W.Kirk,etal.DevelopmentofHydrogenStorageforFuelCellGeneratorsI:HydrogenGenerationUsingHydrolysisHydrides[J].InternationalJournalofHydrogenEnergy,1999,24:665~675. [5]J.Tanski.AnalysisofaNewReactionMechanismforHydrolysisofLiH[R].LosAlamosNationalLaboratory,LAUR-00-5324,2000. [6]C.Haertling,R.J.HanrahanJr,R.Smith.ALiteratureReviewofReactionsandKineticsofLithiumHydrideHydrolysis[J].JournalofNuclearMaterials,2006,349:195~233. [7]C.Maupoix,J.L.Houzelot,E.Sciora,G,etal.ExperimentalInvestigationoftheGrainSizeDependenceoftheHydrolysisofLiHPowder[J].PowderTechnology,2010,6:1~6. [8]R.P.Awbery,D.A.Broughton,S.C.Tsang.InSituObservationofLithiumHydrideHydrolysisbyDRIFTSpectroscopy[J].JournalofNuclearMaterials,2008,373:94~102. [9]K.V.WilsonJr,B.M.Patterson,J.Phillips.MicrobalanceStudyoftheCorrosionKineticsofLithiumHydridebyWater[J].JournalofNuclear Materials,2008,374:229~240. [10]O.Levenspiel.ChemicalReactionEngineering[A],3rdEd.JohnWiley[C].NewYork,1998. [11]R.V.Lukashev,N.A.Yakovleva,S.N.Klyamkin,eta1.EffectofMechanicalActivationontheReactionofMagnesiumHydridewithWater.2008,53(3):343~349. [16]L.X.HU,E.D.WANG.HydrogenGenerationViaHydrolysisofNanocrystallineMgH2andMgH2-basedComposites.Trans.NonferrousMet.2005,15(5). [17]李李泉,朱云峰,沈品.一种水解制氢用镁基氢化物复合体系及其制备方法和应用[P].中国:101811667,2010. [18]J.P.Tessier,P.Palau,J.Huot.HydrogenProductionandCrystalStructureofBall-milledMgH2CaandMgH2CaHMixtures[J].JournalofAlloysandCompounds,2004,376:180~185. [19]M.H.Grosjean,L.ROU.HydrolysisofMgsaltandMgH2saltMixturesPreparedbyBallMillingforHydrogenProduction[J].AlloysComp,2006,416:296~302. [20]V.D.Makhaev,L.A.Petrova,B.P.Tarasov.HydrolysisofMagnesiumHydrideinthePresenceofAmmoniumSalts[J].RussJInorgChem,2008,53(6):858~860. [21]Y.Ykojima,K.I.Suzuki,Y.Kawai.HydrogenGenerationbyHydrolysisReactionofMagnesiumhydride[J].J.MaterScience,2004,39:2227~2229. [22]V.C.Y.Kong,D.W.Kirk,F.R.Foulkes,etal.DevelopmentofhydrogenstorageforfuelcellgeneratorsII:utilizationofcalciumhydrideandlithiumhydride[J].InternationalJournalofHydrogenEnergy,2003,28:205~214 |
以上是毕业论文任务书,课题毕业论文、开题报告、外文翻译、程序设计、图纸设计等资料可联系客服协助查找。