1. 毕业设计(论文)的内容和要求
本课题以可传导氯离子的固态聚合物电解质为研究对象,通过设计、制备固态聚合物电解质,通过调控固态聚合物电解质的组成,深入研究其物理性能、化学稳定性和电化学特性,分析电解质中各组分间的相互作用,并构建基于固态聚合物电解质的氯离子电池体系,理解固态聚合物电解质中氯离子传导机制,希望可以改善电池性能。
最后把整个研究内容写成毕业论文。
毕业论文的内容和要求如下:(1)在第1章引言部分,通过文献阅读和总结分析,给出如下内容:氯离子电池的原理和方法,氯离子电池的研究现状,现有氯离子电池体系存在的问题或不足,本课题拟开展的研究内容和预期目标。
2. 参考文献
[1] X Zhao, S Ren, M Bruns, et al., Chloride ion battery: a new member in the rechargeable battery family, Journal of Power Sources, 245 (2014) 706-711. [2] F Gschwind, H Euchner, G Rodriguez-Garcia, Chloride ion battery review: theoretical calculations, state of the art, safety, toxicity, and an outlook towards future developments, European Journal of Inorganic Chemistry, 21 (2017) 27842799. [3] X Zhao, Z Zhao-Karger, D Wang, et al., Metal oxychlorides as cathode materials for chloride ion batteries. Angewandte Chemie International Edition, 52 (2013) 13621-13624. [4] P G Tan, R Xu, Z Xing, et al., Burning lithium in CS2 for high-performing compact Li2S-graphene nanocapsules for Li-S batteries, Nature Energy, 2 (2017) 17090. [5] T Yu, L Qiang, X Zhao, et al., Nanoconfined iron oxychloride material as high performance cathode for rechargeable chloride ion battery, ACS Energy Letters, 2 (2017) 2341-2348. [6] X Zhao, Z Zhao, M Yang, et al., Developing polymer cathode material for the chloride ion battery, ACS Applied Materials Interfaces, 9 (2017) 2535-2540. [7] X Zhao, Q Li, Z Zhao-Karger, et al., Magnesium anode for chloride ion batteries, ACS Applied Materials Interfaces, 6 (2014) 10997. [8] C E Derrington, A Lindner, M O'Keeffe, Ionic conductivity of some alkaline earth halides, Journal of Solid State Chemistry, 15 (1975) 171-174. [9] I Nobuhito, O Koji, A Gin-Ya, Water-insoluble lanthanum oxychloride-based solid electrolytes with ultra-high chloride ion conductivity, Angewandte Chemie International Edition, 41 (2002) 3890-3892. [10] M Armand, The history of polymer electrolytes, Solid State Ionics, 69 (1994) 309-319. [11] D E Fenton, J M Parker, P V Wright, Complexes of alkali metal ions with poly(ethylene oxide), Polymer, 14 (1973) 589. [12] Y Li, K W Wong, Q Dou, et al., A single-ion conducting and shear-thinning polymer electrolyte based on ionic liquid-decorated PMMA nanoparticles for lithium metal batteries, Journal of Materials Chemistry A, 4 (2016) 18543-18550 [13] J B Goodenough, P Singh, Review-solid electrolytes in rechargeable electrochemical cells, Journal of The Electrochemical Society, 162 (2015) A2387-A2392. [14] L C Hardy, D F Shriver, Preparation and electrical response of solid polymer electrolytes with only one mobile species, Journal of the American Chemical Society, 107 (1985) 3823-3828 [15] P C Huang, K H Reichert, Polymerization of diallyldimethylammonium chloride in inverse emulsion, II molecular-weight and electrical-conductivity of the polymer, Macromolecular Materials Engineering, 165 (1989) 1-7.
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