1. 毕业设计（论文）的内容和要求
本课题在理解氯离子电池研究背景、掌握其电极材料研究概况以及分析相关研究存在的问题的基础上。
通过热分解及随后的热处理制备氯氧化铁正极材料，进一步通过液相插层法制得具有大层间距的FeOCl材料。
表征插层前后材料的微结构；将所制备的氯氧化铁材料制成电极，以复合离子液体为电解液，金属锂为负极，组装电池，研究层结构调控对氯氧化铁正极电化学储氯性能的影响。
2. 参考文献
根据毕业要求指点3.1，毕设期间要进行研究现状调查与总结，要求在开题报告及毕业设计（论文）中涉及的英文文献不少于20篇，其中近5年不少于8篇，英文文献不少于5篇。
以下是与本课题相关的部分文献列表： [1] Zhao, X.Y., et al., Metal Oxychlorides as Cathode Materials for Chloride Ion Batteries [J]. Angewandte Chemie-International Edition 2013,52(51): 13621-13624.[2] Gao, P., et al., Vanadium Oxychloride/Magnesium Electrode Systems for Chloride Ion Batteries [J]. ACS Applied Materials Interfaces 2014, 6(24): 22430-22435.[3] Zhao, X.Y., et al., Magnesium Anode for Chloride Ion Batteries [J]. ACS Applied Materials Interfaces 2014, 6(14): 10997-11000.[4] Zhao, X.Y., et al., Chloride ion battery: A new member in the rechargeable battery family [J]. Journal of Power Sources 2014, 245: 706-711.[5] Gao, P., et al., VOCl as a Cathode for Rechargeable Chloride Ion Batteries [J]. Angewandte Chemie-International Edition 2016, 55(13): 4285-4290.[6] Gschwind, F., et al., Facile Preparation of Chloride-Conducting Membranes: First Step towards a Room-Temperature Solid-State Chloride-Ion Battery [J]. Chemistryopen 2016, 5(6): 525-530.[7] Zhao, X.Y., et al., Carbon incorporation effects and reaction mechanism of FeOCl cathode materials for chloride ion batteries [J]. Scientific Reports 2016, 6: 19448.[8] Chen, F., Z.Y. Leong, and H.Y. Yang, An aqueous rechargeable chloride ion battery [J]. Energy Storage Materials 2017, 7: 189-194.[9] Gschwind, F., H. Euchner, and G. Rodriguez-Garcia, Chloride Ion Battery Review: Theoretical Calculations, State of the Art, Safety, Toxicity, and an Outlook towards Future Developments [J]. European Journal of Inorganic Chemistry 2017, 2017(21): 2784-2799.[10] Wang, D., et al., Investigation of chloride ion adsorption onto Ti2C MXene monolayers by first-principles calculations [J]. Journal of Materials Chemistry A 2017, 5(47): 24720-24727.[11] Yu, T., et al., Nanoconfined Iron Oxychloride Material as a High-Performance Cathode for Rechargeable Chloride Ion Batteries [J]. ACS Energy Letters 2017, 2(10): 2341-2348.[12] Zhao, X., et al., Developing Polymer Cathode Material for the Chloride Ion Battery [J]. ACS Applied Materials Interfaces, 2017, 9(3): 2535-2540.[13] Zhao, Z., et al., Chloride ion-doped polyaniline/carbon nanotube nanocomposite materials as new cathodes for chloride ion battery [J]. Electrochimica Acta 2018, 270: 30-36.[14] Hu, X., et al., Electrochemical Performance of Sb4O5Cl2 as a New Anode Material in Aqueous Chloride-Ion Battery [J]. ACS Applied Materials Interfaces 2019, 11(9): 9144-9148.[15] Chen, C., et al., An All-Solid-State Rechargeable Chloride Ion Battery [J]. Advanced Science 2019, 6(6): 1802130.[16] Kong, H., et al., Polypyrrole as a Novel Chloride‐Storage Electrode for Seawater Desalination [J]. Energy Technology 2019, 7(11): 1900835.[17] Yan, Q., et al., Vanadium oxychloride as cathode for rechargeable aluminum batteries [J]. Journal of Alloys and Compounds 2019, 806: 1109-1115.[18] Yang, R., T. Yu, and X. Zhao, Polypyrrole-coated iron oxychloride cathode material with improved cycling stability for chloride ion batteries [J]. Journal of Alloys and Compounds 2019, 788: 407-412.[19] Yu, T., et al., Polyaniline-Intercalated FeOCl Cathode Material for Chloride-Ion Batteries [J]. ChemElectroChem 2019, 6(6): 1761-1767.
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