1. 毕业设计(论文)的内容和要求
固体氧化物电解池(solid oxide electrolysis cell,SOEC)是一种能在高温下将热能和电能高效环保地直接转化为燃料中化学能的全固态化学电解装置。
SOEC可在高温下直接将CO2电解成CO,在当前能源和环境问题日益凸显的社会背景下,SOEC 技术必将具有广阔的应用前景。
电解池通常由燃料极,电解质和空气极组成,CO2在燃料极一侧完成吸附和脱附过程,因此燃料极通常是最关键的一环。
2. 参考文献
根据毕业要求,毕设期间要进行研究现状调查与总结,要求在开题报告及毕业设计(论文)中涉及的英文文献不少于20篇,其中近5年不少于8篇,英文文献不少于5篇。
以下是与本课题相关的部分文献列表: [1] DU Z, ZHAO H, YI S, et al. High-Performance Anode Material Sr2FeMo0.65Ni0.35O6-δ with In Situ Exsolved Nanoparticle Catalyst [J]. ACS nano, 2016, 10(9): 8660-8669.[2] KIM G S, LEE B Y, ACCARDO G, et al. Improved catalytic activity under internal reforming solid oxide fuel cell over new rhodium-doped perovskite catalyst [J]. Journal of Power Sources, 2019, 423(305-315).[3] KYRIAKOU V, NEAGU D, PAPAIOANNOU E I, et al. Co-electrolysis of H2O and CO2 on exsolved Ni nanoparticles for efficient syngas generation at controllable H2/CO ratios [J]. Applied Catalysis B: Environmental, 2019, 258(117950).[4] LI J, WEI B, YUE X, et al. Morphology evolution and exsolution mechanism of a partially decomposed anode for intermediate temperature-solid oxide fuel cells [J]. Electrochimica Acta, 2019, 304(30-41).[5] LI J, WEI B, YUE X, et al. A Highly Efficient and Robust Perovskite Anode with Iron-Palladium Co-exsolutions for Intermediate-Temperature Solid-Oxide Fuel Cells [J]. ChemSusChem, 2018, 11(15): 2593-603.[6] NEAGU D, OH T S, MILLER D N, et al. Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution [J]. Nature communications, 2015, 6(8120).[7] NEAGU D, TSEKOURAS G, MILLER D N, et al. In situ growth of nanoparticles through control of non-stoichiometry [J]. Nature chemistry, 2013, 5(11): 916-923.[8] PARK S, KIM Y, HAN H, et al. In situ exsolved Co nanoparticles on Ruddlesden-Popper material as highly active catalyst for CO2 electrolysis to CO [J]. Applied Catalysis B: Environmental, 2019, 248(147-156).[9] TIAN Y, ZHANG L, JIA L, et al. Novel quasi-symmetrical solid oxide electrolysis cells with in-situ exsolved cathode for CO2 electrolysis [J]. Journal of CO2 Utilization, 2019, 31(43-50).[10] XU Z, LI Y, WAN Y, et al. Nickel enriched Ruddlesden-Popper type lanthanum strontium manganite as electrode for symmetrical solid oxide fuel cell [J]. Journal of Power Sources, 2019, 425(153-161).
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