1. 毕业设计（论文）的内容和要求
本课题以制备MOP作为分散主体的孔性液体为基础，通过低碳烷烃吸附的策略，利用其独特的选择性吸收为主，研究孔性液体的吸附分离性能，并应用于低碳烷烃的分离研究。
对所获得的孔性液体的物理化学性质进行表征，深入探究孔性液体的孔结构、组成以及对气体吸附的规律。
在高压环境下测定孔性液体对CH4、CO2、等的吸收性能，并进行相关评价。
2. 参考文献
[1] James S L, The Dam Bursts for Porous Liquids [J]. Advanced Materials 2016,28:5712-6.[2] Oreilly N, Giri N, James S L, Porous liquids [J]. Chemistry-A European Journal 2007,13:3020-5.[3]Kim, Selvapalam, Ko, et al, Functionalized cucurbiturils and their applications [J]. Chemical Society Reviews 2007:267-279.Society Reviews 2007: 267-279[4] Petit,C, Lin,et al, Design and characterization of liquidlike poss-based hybrid nanomaterials synthesized via ionic bonding and their interactionswith CO2[J]. Langmuir 2013:12234-12242.[5] Giri N, Del Popolo M G, Melaugh G, et al., Liquids with permanent porosity [J]. Nature2015, 527:216-20.[6]Giri N, Davidson C E, Melaugh G, et al, Alkylated organic cages: from porous crystals to neat liquids [J]. Chemical Science 2012,3:2153.[7]Gaillac R, Pullumbi P, Beyer K A, et al, Liquid metal-organic frameworks [J]. Nature materials2017,16:1149-1154.[8] Zhang J, Chai S H, Qiao Z A, et al, Porous liquids:a promising class of media for gas separation[J]. Angewandte Chemie International Edition 2015,54:932-6.[9]Shi T, Zheng Y, Wang T, et al., Effect of Pore Size on the Carbon Dioxide Adsorption Behavior of Porous Liquids Based on Hollow Silica [J]. Chemphyschem 2018,19:130-137.[10]Peipei L,A. SJ, Jinshui Z, et al, Electrostatic-Assisted Liquefaction of Porous Carbons [J].Angewandte Chemie International Edition 2017,129:15154-15158.[11] Banerjee R, Phan A, Wang B, et al, High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2capture [J]. Science 2008,319:939-943.[12]Zhang F, Yang F, Huang J, et al, Thermodynamics and Kinetics of Gas Storage in Porous Liquids [J]. Journal of Physical Chemistry B 2016,120:7195-200.
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