1. 毕业设计(论文)的内容和要求
金属有机骨架材料(Metal-Organic Frameworks,MOFs)是一类高度多孔的材料,由有机配体桥接的金属簇构成。
与传统的多孔材料相比,MOF具有多种独特的特性,例如高表面积,多样的组成以及易于功能化。
这些特性引起了各个领域的重大研究兴趣1-4。
2. 参考文献
1. Huang, Y. B.;Liang, J.;Wang, X. S.; Cao, R., Multifunctional metal-organic framework catalysts: synergistic catalysis and tandem reactions. Chem Soc Rev 2017, 46 (1), 126-157.2. Li, R.;Zhang, W.; Zhou, K., Metal-Organic-Framework-Based Catalysts for Photoreduction of CO2. Adv Mater 2018, e1705512.3. Zhao, X.;Wang, Y.;Li, D. S.;Bu, X.; Feng, P., Metal-Organic Frameworks for Separation. Adv Mater 2018, e1705189.4. Zhao, M.;Yuan, K.;Wang, Y.;Li, G.;Guo, J.;Gu, L.;Hu, W.;Zhao, H.; Tang, Z., Metal-organic frameworks as selectivity regulators for hydrogenation reactions. Nature 2016, 539 (7627), 76-80.5. Liu, J.;Chen, L.;Cui, H.;Zhang, J.;Zhang, L.; Su, C. Y., Applications of metal-organic frameworks in heterogeneous supramolecular catalysis. Chem Soc Rev 2014, 43 (16), 6011-61.6. Chughtai, A. H.;Ahmad, N.;Younus, H. A.;Laypkov, A.; Verpoort, F., Metal-organic frameworks: versatile heterogeneous catalysts for efficient catalytic organic transformations. Chem Soc Rev 2015, 44 (19), 6804-49.7. Zhang, Q.;Li, B.; Chen, L., First-principles study of microporous magnets M-MOF-74 (M = Ni, Co, Fe, Mn): the role of metal centers. Inorg Chem 2013, 52 (16), 9356-62.8. Valvekens, P.;Vermoortele, F.; De Vos, D., Metalorganic frameworks as catalysts: the role of metal active sites. Catalysis Science Carbonell, E.;Ferrer, B.;Llabres i Xamena, F. X.; Garcia, H., Semiconductor behavior of a metal-organic framework (MOF). Chemistry 2007, 13 (18), 5106-12.10. Tejeda-Serrano, M.;Mon, M.;Ross, B.;Gonell, F.;Ferrando-Soria, J.;Corma, A.;Leyva-Perez, A.;Armentano, D.; Pardo, E., Isolated Fe(III)-O Sites Catalyze the Hydrogenation of Acetylene in Ethylene Flows under Front-End Industrial Conditions. J Am Chem Soc 2018, 140 (28), 8827-8832.11. Wu, H.;Chua, Y. S.;Krungleviciute, V.;Tyagi, M.;Chen, P.;Yildirim, T.; Zhou, W., Unusual and highly tunable missing-linker defects in zirconium metal-organic framework UiO-66 and their important effects on gas adsorption. J Am Chem Soc 2013, 135 (28), 10525-32.12. Liang, Z.;Qu, C.;Xia, D.;Zou, R.; Xu, Q., Atomically Dispersed Metal Sites in MOF-Based Materials for Electrocatalytic and Photocatalytic Energy Conversion. Angewandte Chemie-International Edition 2018, 57 (31), 9604-9633.13. Dhakshinamoorthy, A.;Asiri, A. M.; Garcia, H., Metal Organic Frameworks as Versatile Hosts of Au Nanoparticles in Heterogeneous Catalysis. ACS Catalysis 2017, 7 (4), 2896-2919.
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