1. 毕业设计(论文)的内容和要求
金属有机框架材料由于其规则的微孔结构,在气体吸附存储展示了潜在的应用,丰富可调的孔道环境吸引了在催化、载药方面等方向的应用。
在这里,利用压力诱导晶型转变的策略将多种功能材料封装到预先合成好的MOF的孔道中。
该新策略经由压力诱导无定形化和后刺激晶态恢复两个过程将外来物种封装于MOF结构中。
2. 参考文献
1. Zhou, H.-C., Long, J. R., Yaghi, O. M. Introduction to MetalOrganic Frameworks. Chem Rev. 112, 673-674(2012).2. Deng, H., Grunder, S., Cordova, K. E., Valente, C., Furukawa, H., Hmadeh, M., et al. Large-Pore Apertures in a Series of Metal-Organic Frameworks. Science. 336, 1018-1023(2012).3. Cui, Y., Yue, Y., Qian, G., Chen, B. Luminescent Functional MetalOrganic Frameworks. Chem Rev. 112, 1126-1162(2012).4. Horcajada, P., Chalati, T., Serre, C., Gillet, B., Sebrie, C., Baati, T., et al. Porous metalorganic-framework nanoscale carriers as a potential platform for drug deliveryand imaging. Nature Mater. 9, 172(2009).5. Zhao, X., Wang, Y., Li, D.-S., Bu, X., Feng, P. MetalOrganic Frameworks for Separation. Adv Mater. 30, 1705189(2018).6. Falcaro, P., Hill, A. J., Nairn, K. M., Jasieniak, J., Mardel, J. I., Bastow, T. J., et al. A new method to position and functionalize metal-organic framework crystals. Nat Commun. 2, 237(2011).7. Falcaro, P., Furukawa, S. Doping Light Emitters into MetalOrganic Frameworks. Angewandte Chemie International Edition. 51, 8431-8433(2012).8. Falcaro, P., Normandin, F., Takahashi, M., Scopece, P., Amenitsch, H., Costacurta, S., et al. Dynamic Control of MOF-5 Crystal Positioning Using a Magnetic Field. Adv Mater. 23, 3901-3906(2011).9. Lu, G., Li, S., Guo, Z., Farha, O. K., Hauser, B. G., Qi, X., et al. Imparting functionality to a metalorganic framework material by controlled nanoparticle encapsulation. Nature Chem. 4, 310(2012).10. Zhao, M., Yuan, K., Wang, Y., Li, G., Guo, J., Gu, L., et al. Metalorganic frameworks as selectivity regulators for hydrogenation reactions. Nat. 539, 76(2016).
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