1. 毕业设计（论文）的内容和要求
基于蓝光聚合物的不稳定性根源问题，通过芴单元不对称功能化，在分子主链的 9 位和 4 位分别引入空间位阻基团 和载流子稠环传输基团，制备一系列高效宽带隙聚芴半导体发光材料，借助侧链芳基载流子传输基团的堆积作用，组装形成分子有序自 封装层，抑制分子主链间的聚集作用，实现单分子机制激发态发光的 同时提高链间的载流子传输特性，构 筑高性能蓝光发光光电子器件。
2. 参考文献
1, Lin, J.; Yu, Z.; Zhu, W.; Xing, G.; Lin, Z.; Yang, S.; Xie, L.; Niu, C.; Huang, W., A [small pi]-conjugated polymer gelator from polyfluorene-based poly(tertiary alcohol) via the hydrogen-bonded supramolecular functionalization. Polymer Chemistry 2013, 4, 477-483.2, Hoeben, F. J. M.; Jonkheijm, P.; Meijer, E. W.; Schenning, A., About supramolecular assemblies of pi-conjugated systems. Chemical Reviews 2005, 105, 1491-1546.3, Evans, R. C., Harnessing self-assembly strategies for the rational design of conjugated polymer based materials. Journal of Materials Chemistry C 2013, 1, 4190-4200. 4, Bai, L.; Liu, B.; Han, Y.; Yu, M.; Wang, J.; Zhang, X.; Ou, C.; Lin, J.; Zhu, W.; Xie, L.; Yin, C.; Zhao, J.; Wang, J.; Bradley, D. D. C.; Huang, W., Steric-Hindrance-Functionalized Polydiarylfluorenes: Conformational Behavior, Stabilized Blue Electroluminescence, and Efficient Amplified Spontaneous Emission. Acs Applied Materials List, E. J. W., Semiconducting polyfluorenes - Towards reliable structure-property relationships. Advanced Materials 2002, 14, 477-487. 6, Yu, M.-N.; Soleimaninejad, H.; Lin, J.-Y.; Zuo, Z.-Y.; Liu, B.; Bo, Y.-F.; Bai, L.-B.; Han, Y.-M.; Smith, T. A.; Xu, M.; Wu, X.-P.; Dunstan, D. E.; Xia, R.-D.; Xie, L.-H.; Bradley, D. D. C.; Huang, W., Photophysical and Fluorescence Anisotropic Behavior of Polyfluorene β-Conformation Films. The Journal of Physical Chemistry Letters 2018, 9, 364-372. 7, Lin, Z.-Q.; Shi, N.-E.; Li, Y.-B.; Qiu, D.; Zhang, L.; Lin, J.-Y.; Zhao, J.-F.; Wang, C.; Xie, L.-H.; Huang, W., Preparation and Characterization of Polyfluorene-Based Supramolecular pi-Conjugated Polymer Gels. Journal of Physical Chemistry C 2011, 115, 4418-4424. 8, Shaw, P. E.; Ruseckas, A.; Peet, J.; Bazan, G. C.; Samuel, I. D. W., Exciton-Exciton Annihilation in Mixed-Phase Polyfluorene Films. Advanced Functional Materials 2010, 20, 155-161.
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