1. 毕业设计(论文)的内容和要求
内容:制备双金属磁性纳米颗粒,通过PTFE为粘结剂制备复合电极;之后探讨其稳定性与催化性能。
要求:掌握电芬顿的原理、水热合成的操作流程;了解材料表征时使用到的大型仪器设备。
2. 参考文献
[1] P. Yuan, X. Mei, B.X. Shen, F.J. Lu, W.J. Zhou, M. Si, S. Chakraborty, Oxidation of NO by in situ Fenton reaction system with dual ions as reagents, Chem. Eng. J. 351 (2018) 660-667.[2] F. Sopaj, N. Oturan, J. Pinson, F. Podvorica, M.A. Oturan, Effect of the anode materials on the efficiency of the electro-Fenton process for the mineralization of the antibiotic sulfamethazine, Appl. Catal. B-Environ. 199 (2016) 331-341.[3] X.W. Zhang, J.L. Fu, Y. Zhang, L.C. Lei, A nitrogen functionalized carbon nanotube cathode for highly efficient electrocatalytic generation of H2O2 in Electro-Fenton system, Sep. Purif. Technol. 64 (2008) 116-123.[4] X.C. Liu, Y.Y. Zhou, J.C. Zhang, L. Luo, Y. Yang, H.L. Huang, H. Peng, L. Tang, Y. Mu, Insight into electro-Fenton and photo-Fenton for the degradation of antibiotics: Mechanism study and research gaps, Chem. Eng. J. 347 (2018) 379-397.[5] W.L. Yang, M.H. Zhou, L. Liang, Highly efficient in-situ metal-free electrochemical advanced oxidation process using graphite felt modified with N-doped graphene, Chem. Eng. J. 338 (2018) 700-708.[6] O. Garcia-Rodriguez, Y.Y. Lee, H. Olvera-Vargas, F.X. Deng, Z.X. Wang, O. Lefebvre, Mineralization of electronic wastewater by electro-Fenton with an enhanced graphene-based gas diffusion cathode, Electrochim. Acta. 276 (2018) 12-20.[7] G.S. Xia, Y.H. Lu, H.B Xu, Electrogeneration of hydrogen peroxide for electro-Fenton via oxygen reduction using polyacrylonitrile-based carbon fiber brush cathode, Electrochim. Acta. 158 (2015) 390-396.[8] E. Brillas, I. Sire靤, M.A. Oturan, Electro-Fenton Process and related electrochemical technologies based on Fenton抯 reaction chemistry, Chem. Rev. 109 (2009) 6570-6631.[9] L.L. Cui, P.P. Ding, M. Zhou, W.H. Jing, Energy efficiency improvement on in situ generating H2O2 in a double-compartment ceramic membrane flow reactor using cerium oxide modified graphite felt cathode, Chem. Eng. J. 330 (2017) 1316-1325.[10] P.P. Ding, L.L. Cui, D. Li, W.H. Jing, An innovative dual-compartment flow reactor coupled with a gas diffusion electrode for in-situ generating H2O2.[11] C. Zhang, L. Zhou, J. Yang, X.M. Yu, Y.H. Jiang, M.H. Zhou, Nanoscale zero-valent iron/AC as heterogeneous Fenton catalysts in three-dimensional electrode system, Environ. Sci. Pollut. R. 21 (2014) 8398-8405.[12] C.C. Lin, S.T. Hsu, Performance of nZVI/H2O2 process in degrading polyvinyl alcohol in aqueous solutions, Sep. Purif. Technol. 203 (2018) 111-116.[13] J.M. Deng, H.R. Dong, C. Zhang, Z. Jiang, Y.J. Cheng, K.J. Hou, L.H. Zhang, C.Z. Fan, Nanoscale zero-valent iron/biochar composite as an activator for Fenton-like removal of sulfamethazine, Sep. Purif. Technol. 202 (2018) 130-137.[14] T.L.P. Dantas, V.P. Mendon鏰, H.J. Jos? A.E. Rodrigues, R.F.P.M. Moreira, Treatment of textile wastewater by heterogeneous Fenton process using a new composite Fe2O3/carbon, Chem. Eng. J. 118 (2006) 77-82.[15] G.K. Zhang, Y.Y. Gao, Y.L. Zhang, Y.D. Guo, Fe2O3-pillared rectorite as an efficient and stable Fenton-like heterogeneous catalyst for photodegradation of organic contaminants, Environ. Sci. Technol, 44 (2010) 6384-6389.[16] M.A. Voinov, J.O.S. Paga靚, E. Morrison, T.I. Smirnova, A.I. Smirnov, Surface-mediated production of hydroxyl radicals as a mechanism of iron oxide nanoparticle biotoxicity, J. Am. Chem. Soc, 133 (2011) 35-41.[17] G.B. Ortiz De La Plata, O.M. Alfano, A.E. Cassano, Decomposition of 2-chlorophenol employing goethite as Fenton catalyst II: Reaction kinetics of the heterogeneous Fenton and photo-Fenton mechanisms, Appl. Catal. B-Environ. 95 (2010) 14-25.
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