高抗冲聚苯乙烯/聚磷酸铵/石墨烯复合材料的设计制备及阻燃性能研究任务书

 2021-10-24 15:27:43

1. 毕业设计(论文)的内容和要求

内容:(1)通过文献调研,了解高抗冲聚苯乙烯复合材料的研究现状,确定高抗冲聚苯乙烯阻燃添加剂的填料配比。

(2)通过实验研究,制得不同填料配比的高抗冲聚苯乙烯复合材料,并获得各样品的极限氧指数、垂直燃烧等级、熔融滴落情况和点燃时间等参数。

(3)通过对实验数据进行研究和分析,揭示高抗冲聚苯乙烯复合材料的阻燃性能随填料配比的变化规律。

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2. 参考文献

[1] J.谢尔斯, D.B.普里迪. 现代苯乙烯系聚合物[M]. 化学工业出版社材料科学与工程出版中心, 2004.[2] 杨荣杰, 王建祺. 聚合物纳米复合物加工、热行为与阻燃性能[M]. 北京:科学出版社, 2010.[3] 彭治汉. 聚合物阻燃新技术[M]. 北京: 化学工业出版社, 2015. [4] Bourbigot S, Duquesne S. Fire retardant polymers: Recent developments and opportunities[J]. Journal of Materials Chemistry, 2007, 17(22): 2283-2300.[5] Laoutid F, Bonnaud L, Alexandre M, et al. New prospects in flame retardant polymer materials: From fundamentals to nanocomposites[J]. Materials Science and Engineering R: Reports, 2009, 63(3): 100-125.[6] 张军, 纪奎江, 夏延致, 等. 聚合物燃烧与阻燃技术[M]. 北京: 化学工业出版社, 2005: 212-213.[7] Wang X, Hu Y, Song L, et al. UV-curable waterborne polyurethane acrylate modified with octavinyl POSS for weatherable coating applications[J]. Journal of Polymer Research, 2011, 18(4): 721-729.[8] Zhang X, Zhu J, Tiwary C S, et al. Palladium nanoparticles supported on nitrogen and sulfur dual-doped graphene as highly active electrocatalysts for formic acid and methanol oxidation[J]. ACS Applied Materials surface: comparison with dissolved form in aqueous environment[J]. Journal of Hazardous Materials, 2017, 324: 321-328.[12] Zhu Y, Murali S, Cai W, et al. Graphene and graphene oxide: Synthesis, properties, and applications[J]. Advanced Materials, 2010, 22(35): 3906-3924.[13] Sang B, Li Z, Li X, et al. Graphene-based flame retardants: a review[J]. Journal of Materials Science, 2016, 51(18): 8271-8295.[14] Idumah C I, Hassan A, Affam A C. A review of recent developments in flammability of polymer nanocomposites[J]. Reviews In Chemical Engineering, 2015, 31(2): 149-177.[15] Nine M J, Tran D N H, Elmekawy A, et al. Interlayer growth of borates for highly adhesive graphene coatings with enhanced abrasion resistance, fire-retardant and antibacterial ability[J]. Carbon, 2017, 117: 252-262.[16] Huang G, Gao J, Wang X, et al. How can graphene reduce the flammability of polymer nanocompo-sites?[J]. Materials Letters, 2012, 66(1): 187-189.[17] Han Y, Wu Y, Shen M, et al. Preparation and properties of polystyrene nanocomposites with graphite oxide and graphene as flame retardants[J]. Journal of Materials Science, 2013, 48(12): 4214-4222.[18] Hao Y B, Hou P, Li G X, et al. Effect of base-deposited graphene oxide on the thermal stabilization of poly(vinyl chloride)[J]. Polymer International, 2016, 65(1): 125-132.[19] 左艳梅, 刘心雨, 傅智盛. 新型无卤阻燃增韧高抗冲聚苯乙烯的制备[J].合成树脂及塑料, 2016, 33(4): 29-32.[20] Jiang W, Hao J, Han Z. Study on the thermal degradation of mixtures of ammonium polyphosphate and a novel caged bicyclic phosphate and their flame retardant effect in polypropylene[J]. Polymer degradation and stability, 2012, 97(4): 632-637.[21] Yuan B, Fan A, Yang M, et al. The effects of graphene on the flammability and fire behavior of intumescent flame retardant polypropylene composites at different flame scenarios[J]. Polymer Degradation and Stability, 2017, 143: 42-56.[22] Demir H,Balkse D,lk S. Influence of surface modification of fillers and polymer on flammability and tensile behavior of polypropylene-composites[J]. Polymer Degradation and Stability, 2006, 91: 1079-1085.[23] Gavgani J N, Adelnia H, Gudarzi M M. Intumescent flame retardant polyurethane/reduced graphene oxide composites with improved mechanical, thermal, and barrier properties[J]. Journal of materials science, 2014, 49(1): 243-254. [24] Amani M, Sharif M, Kashkooli A, et al. Effect of mixing conditions on the selective localization of graphite oxide and the properties of polyethylene/high-impact polystyrene/graphite oxide nanocomposite blends[J]. RSC Advances, 2015, 5(95): 77723-77733.

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