1. 毕业设计(论文)的内容和要求
本课题从基础研究的角度出发,通过氢化燃烧合成法合成了Mg2NiH4,并通过机械球磨法复合制备了MgMg2NiH4水解体系,利用自制水解装置测试其水解性能。
重点考察Mg2NiH4添加量、球磨时间、温度等对体系水解性能的影响,通过XRD、XPS、FESEM等测试手段,对水解复合物及水解产物进行表征,并进一步解释该体系的水解机理。
最后把整个研究内容写成毕业论文。
2. 参考文献
根据毕业要求指标点10.2,毕设期间要进行研究现状调查与总结,要求在开题报告及毕业设计(论文)中涉及的英文文献不少于20篇,其中近5年不少于8篇,英文文献不少于5篇。
以下是与本课题相关的部分文献列表:(提供适当参考文献,学生自己按需补充)[1]. Dunn, S., Hydrogen futures: toward a sustainable energy system. International Journal of Hydrogen Energy, 2002. 27(3): p. 235-264.[2]. Zhao, Z., Y. Zhu and L. Li, Efficient catalysis by MgCl2 in hydrogen generation via hydrolysis of Mg-based hydride prepared by hydriding combustion synthesis. Chemical Communications, 2012. 48(44): p. 5509.[3]. Neef, H.J., International overview of hydrogen and fuel cell research☆. Energy, 2009. 34(3): p. 327-333.[4]. Tegel, M., et al., An efficient hydrolysis of MgH2-based materials. International Journal of Hydrogen Energy, 2016. 42(4): p. 2167-2176.[5]. Hiroi, S., S. Hosokai and T. Akiyama, Ultrasonic irradiation on hydrolysis of magnesium hydride to enhance hydrogen generation. International Journal of Hydrogen Energy, 2010. 36(2): p. 1442-1447.[6]. Huang, X., et al., A review: Feasibility of hydrogen generation from the reaction between aluminum and water for fuel cell applications. Journal of Power Sources, 2012. 229: p. 133-140.[7]. Retnamma, R., A.Q. Novais and C.M. Rangel, Kinetics of hydrolysis of sodium borohydride for hydrogen production in fuel cell applications: A review. International Journal of Hydrogen Energy, 2011. 36(16): p. 9772-9790.[8]. Chai, Y.J., et al., Hydrogen generation by aluminum corrosion in cobalt (II) chloride and nickel (II) chloride aqueous solution. Energy, 2014. 68: p. 204-209.[9]. Li, P., et al., Hydrogen Generation Performance of Novel Al-LiH-Metal Oxides. 2018.[10]. Tessier, J.P., et al., Hydrogen production and crystal structure of ball-milled MgH2Ca and MgH2CaH2 mixtures. Journal of Alloys and Compounds, 2003. 376(1-2): p. 180-185.[11]. Liu, Y., et al., Investigation on the improved hydrolysis of aluminumcalcium hydride-salt mixture elaborated by ball milling. Energy, 2015. 84: p. 714-721.[12]. Al Bacha, S., et al., Hydrogen generation via hydrolysis of ball milled WE43 magnesium waste. International Journal of Hydrogen Energy, 2019. 44(33): p. 17515-17524.[13]. Awad, A.S., et al., Effect of carbons (G and CFs), TM (Ni, Fe and Al) and oxides (Nb 2 O 5 and V 2 O 5 ) on hydrogen generation from ball milled Mg-based hydrolysis reaction for fuel cell. Energy, 2015. 95: p. 175-186.[14]. Mao, J., et al., Hydrogen storage and hydrolysis properties of core-shell structured Mg-MFx (M=V, Ni, La and Ce) nano-composites prepared by arc plasma method. Journal of Power Sources, 2017. 366: p. 131-142.[15]. Hiroi, S., S. Hosokai and T. Akiyama, Ultrasonic irradiation on hydrolysis of magnesium hydride to enhance hydrogen generation. International Journal of Hydrogen Energy, 2010. 36(2): p. 1442-1447.[16]. Ma, M., et al., Air-stable hydrogen generation materials and enhanced hydrolysis performance of MgH 2 -LiNH 2 composites. Journal of Power Sources, 2017. 359: p. 427-434.[17]. Oh, S., et al., Design of MgNi alloys for fast hydrogen generation from seawater and their application in polymer electrolyte membrane fuel cells. International Journal of Hydrogen Energy, 2016. 41(10): p. 5296-5303.[18]. Alasmar, E., et al., Hydrogen generation from Nd-Ni-Mg system by hydrolysis reaction. Journal of Alloys and Compounds, 2017. 740: p. 52-60.[19]. Grosjean, M.H., M. Zidoune and L. Rou, Hydrogen production from highly corroding Mg-based materials elaborated by ball milling. Journal of Alloys and Compounds, 2005. 404-406: p. 712-715.[20]. Liu, Y., et al., Hydrogen generation from the hydrolysis of Mg powder ball-milled with AlCl3. Energy, 2013. 53: p. 147-152.[21]. Uan, J., et al., Evolution of hydrogen from magnesium alloy scraps in citric acid-added seawater without catalyst. International Journal of Hydrogen Energy, 2009. 34(15): p. 6137-6142.[22]. Gan, D., et al., Kinetic performance of hydrogen generation enhanced by AlCl3 via hydrolysis of MgH2 prepared by hydriding combustion synthesis. International Journal of Hydrogen Energy, 2018. 43(22): p. 10232-10239.[23]. Yang, B., et al., Enhanced hydrogenation and hydrolysis properties of core-shell structured Mg-MOx (M=Al, Ti and Fe) nanocomposites prepared by arc plasma method. Chemical Engineering Journal, 2019. 371: p. 233-243.[24]. UAN, J., C. CHO and K. LIU, Generation of hydrogen from magnesium alloy scraps catalyzed by platinum-coated titanium net in NaCl aqueous solution. International Journal of Hydrogen Energy, 2007. 32(13): p. 2337-2343.[25]. Gao, S., et al., Effects of nano-composites (FeB, FeB/CNTs) on hydrogen storage properties of MgH2. Journal of Power Sources, 2019. 438: p. 227006.
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