1. 毕业设计（论文）的内容和要求
本课题通过对现有各种热分析仪器的学习掌握，运用其对典型偶氮苯类危险化学品的热危险性开展实验研究，继而根据实验结果对偶氮苯类引发剂热安全性进行分析评价，达到预测典型偶氮苯类危险化学品热安全性的目的。
毕业设计内容和要求设计如下：1、毕业设计的任务内容：⑴学习与热分析相关的基础理论知识，掌握TG、DSC等热分析设备的操作方法、各自特点等，明确其适用范围及优缺点；⑵调研与偶氮类危险化学品有关的文献资料，重点调研偶氮类危险化学品热分解性能相关的资料；⑶制定合理的实验方案，运用上述热分析仪器对2~3种偶氮苯类危险化学品进行热分析实验测试；⑷根据实验结果计算2~3种偶氮苯类危险化学品的热解动力学和热力学参量；⑸评估偶氮苯类危险化学品的热安全性；⑹撰写毕业论文。
2、毕业设计的任务要求：⑴仔细阅读1本以上热分析类书籍，熟练掌握TG、DSC等热分析设备的设计原理和操作方法以及数据处理方法；⑵按照所学方法检索阅读25篇以上文献，中文和英文文献精读数量各自在5篇以上，完成翻译，撰写开题报告；⑶根据实验方案制定的条件测试2~3种偶氮苯类危险化学品的热分解性能；⑷利用原始数据处理计算出原油混容物的活化能、指前因子等反应动力学参量和反应热等热力学参量；论文字数不少于1万字；中英文摘要字数为200～300；参考文献格式符合GB 7714-2005《文后参考文献著录规则》要求。
2. 参考文献
[1]Ma Y Y, Peng H L, Zhang J. Thermal Decomposition and Kinetic Characteristics of Diisopropyl Azodicarboxylate[J]. Safety and environmental engineering, 2019, 26(03): 176-181 192.[2]estk J. The quandary aspects of non-isothermal kinetics beyond the ICTAC kinetic committee recommendations[J]. Thermochimica Acta, 2015, 611: 26-35.[3]Liu S H, Chen Y C, Hou H Y. Thermal runaway hazard studies for ABVN mixed with acids or alkalines by DSC, TAM III, and VSP2[J]. Journal of Thermal Analysis and Calorimetry, 2015, 122(3): 1107-1116.[4]Vyazovkin S, Chrissafis K, Lorenzo M L D, et al. ICTAC Kinetics Committee recommendations for collecting experimental thermal analysis data for kinetic computations[J]. Thermochimica Acta, 2014, 590: 1-23.[5]Guo S, Wan W, Chen C, et al. Thermal decomposition kinetic evaluation and its thermal hazards prediction of AIBN[J]. Journal of thermal analysis and calorimetry, 2013, 113(3): 1169-1176.[6]Vyazovkin S, Burnham A K, Criado J M, et al. ICTAC Kinetics Committee recommendations for performing kinetic computations on thermal analysis data[J]. Thermochimica Acta, 2011, 520: 1-19.[7]United Nations. Committee of Experts on the Transport of Dangerous Goods. Recommendations on the transport of dangerous goods: model regulations[M]. United Nations Publications, 2009: 32-39.[8]Dickinson C F, Heal G R. A review of the ICTAC Kinetics Project, 2000 Part 1. Isothermal results[J]. Thermochimica Acta, 2009, 494: 1-14.[9]Dickinson C F, Heal G R. A review of the ICTAC Kinetics Project, 2000 Part 2. Non-isothermal results[J]. Thermochimica Acta, 2009, 494: 15-25.[10]孙金华, 丁辉. 化学物质热危险性评价[M]. 北京: 科学出版社, 2005.[11]Starink M J. The determination of activation energy from linear heating rate experiments: a comparison of the accuracy of isoconversion methods[J]. Thermochimica Acta, 2003, 404: 163-176.[12]Brown M E, Galwey A K. The significance of compensation effects appearing in data published in computational aspects of kinetic analysis: ICTAC project, 2000[J]. Thermochimica Acta, 2002, 387: 173-183.[13]胡荣祖, 史启祯. 热分析动力学[M]. 北京: 科学出版社, 2001.[14]Roduit B. Computational aspects of kinetic analysis. Part E: The ICTAC Kinetics Project -- numerical techniques and kinetics of solid state processes[J]. Thermochimica Acta, 2000, 355: 171-180.[15]Burnham A K. Computational aspects of kinetic analysis. Part D: The ICTAC Kinetics Project -- multi-thermal-history model-fitting methods and their relation to isoconversional methods[J]. Thermochimica Acta, 2000, 355: 165-170.[16]Vyazovkin S. Computational aspects of kinetic analysis. Part C. The ICTAC Kinetics Project -- the light at the end of the tunnel?[J]. Thermochimica Acta, 2000, 355: 155-163.[17]Maciejewski M. Computational aspects of kinetic analysis. Part B: The ICTAC Kinetics Project -- the decomposition kinetics of calcium carbonate revisited, or some tips on survival in the kinetic minefield[J]. Thermochimica Acta, 2000, 355: 145-154.[18]Brown M E, Maciejewski M, Vyazovkin S, et al. Computational aspects of kinetic analysis Part A: The ICTAC Kinetics Project -- data, methods and results[J]. Thermochimica Acta, 2000, 355: 125-143.[19]Ozawa T. Thermal analysis -- review and prospect[J]. Thermochimica Acta, 2000, 355: 35-42.[20]Li Y F, Hasegawa K. On the thermal decomposition mechanism of self-reactive materials and the evaluating method for the SADTs. 9th international symposium on Loss prevention and safety promotion in the process industries, Barcelona ,1998.Kotoyori T. Critical ignition temperatures of chemical substances[J]. Journal of Loss Prevention in the Process Industries, 1989, 2: 16-21.
以上是毕业论文任务书，课题毕业论文、开题报告、外文翻译、程序设计、图纸设计等资料可联系客服协助查找。
