从晶体结构分析Al对Mg吸放氢性能的调控任务书

 2021-10-25 21:02:03

1. 毕业设计(论文)的内容和要求

本课题在HCS氢致Al*研究的基础上,拟从晶体结构的角度分析Al对Mg吸放氢的作用,主要从物相组成、晶格应力、晶格缺陷等角度来阐明Al对Mg基合金吸放氢过程的调控机理。

通过该毕业论文,能够系统培养学生文献检索和阅读、实验设计和实践、设备操作、数据归纳整理、理论验证、论文撰写等能力,提高学生理论研究和实践技能及分析解决复杂问题的综合素质。

本毕业课题包含以下具有科学价值的问题:1. 氢致Al*的特殊晶体结构;2. Mg-Al合金吸放氢过程中晶体结构的演变; 3. Mg/MgH2与Al的界面结构对其吸放氢性能的影响。

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2. 参考文献

[1] H.Y. Shao, L.Q. He, H.J. Lin, H.W. Li, Progress and Trends in Magnesium-Based Materials for Energy-Storage Research: A Review, Energy Technology, 6 (2018) 445-458.[2] H. Wang, H.J. Lin, W.T. Cai, L.Z. Ouyang, M. Zhu, Tuning kinetics and thermodynamics of hydrogen storage in light metal element based systems A review of recent progress, Journal of Alloys and Compounds, 658 (2016) 280-300.[3] X.T. Huang, A.P. Tao, J. Guo, W.L. Wei, J. Guo, Z.Q. Lan, Synergistic effect of TiF3@ graphene on the hydrogen storage properties of Mg-Al alloy, International Journal of Hydrogen Energy, 43 (2018) 1651-1657.[4] Z.Q. Lan, Z.Z. Sun, Y.C. Ding, H. Ning, W.L. Wei, J. Guo, Catalytic action of Y2O3@graphene nanocomposites on the hydrogen-storage properties of Mg-Al alloys, Journal of Materials Chemistry A, 5 (2017) 15200-15207.[5] J.C. Liu, Y.N. Liu, Z.B. Liu, Z.L. Ma, Y.J. Ding, Y.F. Zhu, Y. Zhang, J.G. Zhang, L.Q. Li, Effect of rGO supported NiCu derived from layered double hydroxide on hydrogen sorption kinetics of MgH2, Journal of Alloys and Compounds, 789 (2019) 768-776.[6] H.Y. Shao, G.B. Xin, J. Zheng, X.G. Li, E. Akiba, Nanotechnology in Mg-based materials for hydrogen storage, Nano Energy, 1 (2012) 590-601.[7] H. Shao, M. Felderhoff, F. Schth, Hydrogen storage properties of nanostructured MgH2/TiH2 composite prepared by ball milling under high hydrogen pressure, International Journal of Hydrogen Energy, 36 (2011) 10828-10833.[8] Y.L. Zhou, Y. Lu, Y.F. Zhu, L.Q. Li, Phase transformation and thermal analysis during combustion synthesis of Mg17Al12 alloy, Rare Metals, 33 (2013) 37-40.[9] S.X. Zhou, T.H. Zhang, N.F. Wang, T. Li, H.L. Niu, H. Yu, D. Liu, Influence of aluminum location on hydrogen sorption kinetics of magnesium-based materials, Functional Materials Letters, 7 (2014) 1450034.[10] Y.Q. Li, H.W. Shang, Y.H. Zhang, P. Li, Y. Qi, D.L. Zhao, Effects of adding nano-CeO2 powder on microstructure and hydrogen storage performances of mechanical alloyed Mg90Al10 alloy, International Journal of Hydrogen Energy, 44 (2019) 1735-1749.[11] Y.Q. Wang, S.X. L, Z.Y. Zhou, W.Z. Zhou, J. Guo, Z.Q. Lan, Effect of transition metal on the hydrogen storage properties of Mg-Al alloy, Journal of Materials Science, 52 (2016) 2392-2399.[12] Y.L. Zhu, S.C. Luo, H.J. Lin, Y.N. Liu, Y.F. Zhu, Y. Zhang, L.Q. Li, Enhanced hydriding kinetics of Mg-10 at% Al composite by forming Al12Mg17 during hydriding combustion synthesis, Journal of Alloys and Compounds, 712 (2017) 44-49.[13] L.T. Zhang, Z.L. Cai, X.Q. Zhu, Z.D. Yao, Z.D. Sun, L. Ji, N.H. Yan, B.B. Xiao, L.X. Chen, Two-dimensional ZrCo nanosheets as highly effective catalyst for hydrogen storage in MgH2, Journal of Alloys and Compounds, 805 (2019) 295-302.[14] Z.Y. Wang, X.L. Zhang, Z.G. Ren, Y. Liu, J.J. Hu, H.W. Li, M.X. Gao, H.G. Pan, Y.F. Liu, In situ formed ultrafine NbTi nanocrystals from a NbTiC solid-solution MXene for hydrogen storage in MgH2, Journal of Materials Chemistry A, 7 (2019) 14244-14252.[15] X.B. Xie, X.J. Ma, P. Liu, J.X. Shang, X.G. Li, T. Liu, Formation of Multiple-Phase Catalysts for the Hydrogen Storage of Mg Nanoparticles by Adding Flowerlike NiS, ACS Applied Materials 10) surface, Applied Surface Science, 464 (2019) 644-650.[17] S.D. House, J.J. Vajo, C. Ren, A.A. Rockett, I.M. Robertson, Effect of ball-milling duration and dehydrogenation on the morphology, microstructure and catalyst dispersion in Ni-catalyzed MgH2 hydrogen storage materials, Acta Materialia, 86 (2015) 55-68.[18] S.C. Luo, H.H. Han, H.X. Huang, J.G. Zhang, Y.N. Liu, Y.F. Zhu, Y. Zhang, B. Xu, L.Q. Li, Effect of Al* generated in situ in hydriding on the dehydriding properties of Mg-Al alloys prepared by hydriding combustion synthesis and mechanical milling, Journal of Alloys and Compounds, 750 (2018) 490-498.[19] S.L. Lee, C.W. Hsu, F.K. Hsu, C.-. Chou, C.K. Lin, C.W. Weng, Effects of Ni addition on hydrogen storage properties of Mg17Al12 alloy, Materials Chemistry and Physics, 126 (2011) 319-324.[20] J. Chen, G.L. Xia, Z.P. Guo, Z.G. Huang, H.K. Liu, X.B. Yu, Porous Ni nanofibers with enhanced catalytic effect on the hydrogen storage performance of MgH2, Journal of Materials Chemistry A, 3 (2015) 15843-15848.

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