Ba0.5Sr0.5Co0.8Fe0.2O3-δ和SrCo0.9Nb0.1O3-δ双层多通道中空纤维膜的制备和性能研究任务书

 2021-10-26 21:58:36

1. 毕业设计(论文)的内容和要求

具体研究内容如下:1. 双层多通道中空纤维膜制备条件影响主要研究相转化纺丝工艺(纺丝液流速、内凝固浴流速、空气距离等)和烧结制度(烧结温度,保温时间等)对膜微观结构的影响。

2. 双层多通道中空纤维膜性能测试与表征主要研究双层结构对中空纤维膜的机械强度、氧渗透性能的影响。

具体要求如下:1、理解气体渗透的基本概念、原理、实验流程图以及影响气体渗透性能的主要因素;2、了解气体渗透膜的基本分类及其所应用的分离体系;3、熟悉钙钛矿氧分离膜制备的常规知识;4、合理安排实验进程,工作时间不迟到早退;5、实验认真仔细,对实验现象进行详细的记录,定期对实验数据进行总结,及时调整实验方案;6、工作积极主动,勤于思考,做好实验室安全卫生工作。

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2. 参考文献

[1] ZHU J, ZHANG G, LIU G, et al. Perovskite Hollow Fibers with Precisely Controlled Cation Stoichiometry via One-Step Thermal Processing [J]. Adv Mater, 2017, 29(18): 6.[2] LI T, WU Z T, LI K. Co-extrusion of electrolyte/anode functional layer/anode triple-layer ceramic hollow fibres for micro-tubular solid oxide fuel cells-electrochemical performance study [J]. J Power Sources, 2015, 273(999-1005.[3] ZHU J W, LIU Z K, GUO S B, et al. Influence of permeation modes on oxygen permeability of the multichannel mixed-conducting hollow fibre membrane [J]. Chem Eng Sci, 2015, 122(614-21.[4] GUO S B, ZHU J W, LIU Z K, et al. Enhanced High Oxygen Permeation of Mixed-Conducting Multichannel Hollow Fiber Membrane via Surface Modified Porous Layer [J]. Ind Eng Chem Res, 2015, 54(27): 6985-92.[5] ZHU J W, DONG Z Y, LIU Z K, et al. Multichannel mixed-conducting hollow fiber membranes for oxygen separation [J]. Aiche J, 2014, 60(6): 1969-76.[6] OTHMAN N H, WU Z T, LI K. Bi1.5Y0.3Sm0.2O3-delta-based ceramic hollow fibre membranes for oxygen separation and chemical reactions [J]. J Membrane Sci, 2013, 432(58-65.[7] WU Z T, THURSFIELD A, METCALFE I, et al. Effects of separation layer thickness on oxygen permeation and mechanical strength of DL-HFMR-ScSZ [J]. J Membrane Sci, 2012, 415(229-36.[8] SETIAWAN L, WANG R, SHI L, et al. Novel dual-layer hollow fiber membranes applied for forward osmosis process [J]. J Membrane Sci, 2012, 421(238-46.[9] OTHMAN M H D, DROUSHIOTIS N, WU Z T, et al. Dual-layer hollow fibres with different anode structures for micro-tubular solid oxide fuel cells [J]. J Power Sources, 2012, 205(272-80.[10] WU Z T, WANG B, LI K. Functional LSM-ScSZ/NiO-ScSZ dual-layer hollow fibres for partial oxidation of methane [J]. Int J Hydrogen Energ, 2011, 36(9): 5334-41.[11] OTHMAN M H D O M H D, DROUSHIOTIS N, WU Z T, et al. Novel fabrication technique of hollow fibre support for micro-tubular solid oxide fuel cells [J]. J Power Sources, 2011, 196(11): 5035-44.[12] OTHMAN M H D, DROUSHIOTIS N, WU Z T, et al. High-Performance, Anode-Supported, Microtubular SOFC Prepared from Single-Step-Fabricated, Dual-Layer Hollow Fibers [J]. Advanced Materials, 2011, 23(21): 2480- .[13] KANAWKA K, OTHMAN M H D, WU Z T, et al. A dual layer Ni/Ni-YSZ hollow fibre for micro-tubular SOFC anode support with a current collector [J]. Electrochem Commun, 2011, 13(1): 93-5.[14] 宫勋,孟秀霞, 杨乃涛等. YSZ/Ni-YSZ双层中空纤维电解质层厚度控制及其影响[J]. 无机材料学报, 2013, 28(10):1108-1114.[15] WU Z T, WANG B, LI K. A novel dual-layer ceramic hollow fibre membrane reactor for methane conversion [J]. J Membrane Sci, 2010, 352(1-2): 63-70.[16] OTHMAN M H D, WU Z T, DROUSHIOTIS N, et al. Single-step fabrication and characterisations of electrolyte/anode dual-layer hollow fibres for micro-tubular solid oxide fuel cells [J]. J Membrane Sci, 2010, 351(1-2): 196-204.[17] DROUSHIOTIS N, OTHMAN M H D, DORASWAMI U, et al. Novel co-extruded electrolyte-anode hollow fibres for solid oxide fuel cells [J]. Electrochem Commun, 2009, 11(9): 1799-802.[18] 张瑛洁, 庄媛媛. 相转化法制备中空纤维陶瓷膜的研究进展[J]. 膜科学与技术, 2015, 35(04): 97-102 .

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