1. 毕业设计（论文）的内容和要求
1.具备基本的有机化学实验操作技能，能进行无水无氧操作。
2.能通过核磁共振、红外光谱，紫外光谱对有机化学无进行结构解析。
3.具备较好的专业英文阅读和写作功底，能熟练阅读和概括文献核心内容。
2. 参考文献
(1) For some selected recent literatures, see: (a) Chen, Z.-M.; Nervig, C. S.; Deluca, R. J.; Sigman, M. S. Palladium-Catalyzed Enantioselective Redox-Relay Heck Alkynylation of Alkenols To Access Propargylic Stereocenters. Angew. Chem. Int. Ed. 2017, 56, 6651-6654. (b) Bernhard, Y.; Thomson, B.; Ferey, V.; Sauthier, M. Nickel-Catalyzed α-Allylation of Aldehydes and Tandem Aldol Condensation/Allylation Reaction with Allylic Alcohols. Angew. Chem. Int. Ed. 2017, 56, 7460-7464. (c) Schlepphorst, C.; Maji, B.; Glorius, F. Ruthenium-NHC Catalyzed α-Alkylation of Methylene Ketones Provides Branched Products through Borrowing Hydrogen Strategy. ACS Catal. 2016, 6, 4184-4188. (d) Kita, Y.; Kavthe, R. D.; Oda, H.; Mashima, K. Asymmetric Allylic Alkylation of β-Ketoesters with Allylic Alcohols by a Nickel/Diphosphine Catalyst. Angew. Chem. Int. Ed. 2016, 55, 1098-1101. (e) Suzuki, Y.; Sun, B.; Sakata, K.; Yoshino, T.; Matsunaga, S.; Kanai, M. Dehydrative Direct C-H Allylation with Allylic Alcohols under [Cp*CoIII] Catalysis. Angew. Chem. Int. Ed. 2015, 54, 9944-9947. (f) Xu, Q.; Chen, J.; Tian, H.; Yuan, X.; Li, S.; Zhou, C.; Liu, J. Catalyst-Free Dehydrative α-Alkylation of Ketones with Alcohols: Green and Selective Autocatalyzed Synthesis of Alcohols and Ketones. Angew. Chem. Int. Ed. 2014, 53, 225-229. (g) Walton, J. W.; Williams, J. M. J. Ruthenium-Catalyzed ortho-Alkylation of Phenols with Alcohols by Dehydrative Coupling. Angew. Chem. Int. Ed. 2012, 51, 12166-12168. (h) Jin, J.; MacMillan, D. W. C. Alcohols as alkylating agents in heteroarene CH functionalization. Nature 2015, 525, 87-90. (i) Terrett, J. A.; Cuthbertson, J. D.; Shurtleff, V. W.; MacMillan, D. W. C. Switching on elusive organometallic mechanisms with photoredox catalysis. Nature 2015, 524, 330-334.
(2) Ma, X.-T.; Dai, R.-H.; Zhang, J.; Gu, Y.; Tian, S.-K. Catalytic Stereospecific Substitution of Enantioenriched Allylic Alcohols with Sodium Sulfinates. Adv. Synth. Catal. 2014, 356, 2984-2988.
(3) Chandasekhar, S.; Jagadeshwar, V.; Saritha, B.; Narsihmulu, C. PalladiumTriethylborane-Triggered Direct and Regioselective Conversion of Allylic Alcohols to Allyl Phenyl Sulfones. J. Org. Chem. 2005, 70, 6506-6507.
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