双亲分子在UHMWPE纤维表面的分子组装及固定任务书

 2021-11-05 19:33:31

1. 毕业设计(论文)的内容和要求

本课题拟通过双亲分子分子自组装,在UHMWPE纤维表面形成一层分子层,然后通过自由基聚合、链转移等方式将双亲分子层固定在纤维表面,从而对UHMWPE纤维表面进行极性处理。

通过改性后的纤维与树脂复合,可以极大提高复合材料的力学性能。

最后把整个研究内容写成毕业论文。

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2. 参考文献

毕设期间要进行研究现状调查与总结,要求在开题报告及毕业设计(论文)中涉及的文献不少于20篇,其中近5年不少于8篇,英文文献不少于5篇。

以下是与本课题相关的部分文献列表:[1] 邱召明. 功能化聚乙烯的制备与表征[D]. 山东: 烟台大学, 2008.[2] 何正洋,潘志娟. 超高分子量聚乙烯纤维的结构与性能[J]. 现代丝绸科学与技术. 2018, 33(4): 5-7.[3] 杨萌,赵宁,徐坚. 超高分子量聚乙烯功能复合材料及其应用[J]. 高分子通报. 2018(08): 25-32.[4] H C C, H P, H Y D. Percolation and resistivity-temperature behaviours of carbon nanotube-carbon black hybrid loaded ultrahigh molecular weight polyethylene composites with segregated structures[J]. The Royal Society of Chemistry. 2015(5): 61318-61323.[5] 马晓星,刘会雪. 聚烯烃材料表面改性研究[J]. 现代工业经济和信息化. 2017, 9(13): 23-25.[6] Li W, Meng L, Wang L. Surface modification of ultra-high molecular weight polyethylene fibers by chromic acid[J]. Surface and Interface Analysis. 2016, 48(12): 1316-1319.[7] Li W, Ma R, Huang M. Surface treatment of ultra-high molecular weight polyethylene fibers using potassium permanganate and mechanical properties of its composites[J]. Surface and Interface Analysis. 2018, 50(1): 65-72.[8] Liston E M, Martinu L, Wertheimer M R.. Plasma surface modification of polymers for improved adhesion: a critical review[J]. Journal of Adhesion Science and Technology. 1993, 7(10): 1091-1127.[9] Hrycak B, Sikora A, Moczala M. Atmospheric Pressure Microwave Argon Plasma Sheet for Wettability Modification of Polyethylene Surfaces[J]. IEEE Transactions on Plasma Science. 2019, 47(2): 1309-1315.[10] Masse P, Cavrot J P, Franois P. Adhesion improvement of high modulus polyethylene fibers by surface plasma treatment: Evaluation by pull‐out testing[J]. Polymer Composites. 1994, 15(3): 247-251.[11] Abdul-Kader A M, Turos A, Radwan R M. Surface free energy of ultra-high molecular weight polyethylene modified by electron and gamma irradiation[J]. Applied Surface Science. 2009, 255(17): 7786-7790.[12] Wang H, Xu L, Li R. Highly hydrophilic ultra-high molecular weight polyethylene powder and film prepared by radiation grafting of acrylic acid[J]. Applied Surface Science. 2016, 382: 162-169.[13] Yoshida H, Mochizuki K, Yamada K. Adhesion of ultrahigh molecular weight polyethylene plates photografted with hydrophilic monomers and evaluation of failure location by X-ray photoelectron spectroscopy[J]. Journal of Applied Polymer Science. 2014, 131(7): 40133.[14] Wang L, Wei J, Zhao K. Preparation and characterization of high-hydrophilic polyhydroxy functional PP hollow fiber membrane[J]. Materials Letters. 2015, 159: 189-192.[15] 王敏. 电晕处理对聚乙烯薄膜热封性能的影响[J]. 上海塑料. 2014(01): 42-45.[16] Kobayashi M, Matsugi T, Saito J. Direct modification of polyolefin films by surface-initiated polymerization of a phosphobetaine monomer[J]. Polym. Chem. 2013, 4(3): 731-739.[17] Zhang Z, Jiang G, Wu Y. Surface functional modification of ultrahigh molecular weight polyethylene fiber by atom transfer radical polymerization[J]. Applied Surface Science. 2018, 427: 410-415.[18] Ruckenstein E, Byungip Chung D. Surface modification by a two-liquid process deposition of AB block copolymers[J]. Journal of Colloid and Interface Science. 1988, 123(1): 170-185.[19] Desai N P, Hubbell J A. Surface Physical Interpenetrating Networks of Polyethylene terephthalate) and Polyethylene oxide) with Biomedical Applications[J]. Macromolecules. 1992, 1(25): 226-232.[20] Yoshida H, Mochizuki K, Yamada K. Adhesion of ultrahigh molecular weight polyethylene plates photografted with hydrophilic monomers and evaluation of failure location by X-ray photoelectron spectroscopy[J]. Journal of Applied Polymer Science. 2014, 131(7): 40133.

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