1. 毕业设计（论文）的内容和要求
内容：（1）设计并合成目标化合物2,4,5-三甲氧基苯甲酰基二苯基氧化膦。
（2）对中间产物及目标化合物进行表征。
（3）研究目标化合物在395 nm LED光源的照射下的稳态光解和对单体三羟甲基丙烷三丙烯酸酯（TMPTA）的固化性能。
2. 实验内容和要求
实验内容：（1）合成α-羟基(2,4,5-三甲氧基苄基)二苯基氧化膦的合成；（2）活性二氧化锰的制备；（3）(2,4,5)-三甲氧基苯甲酰基二苯基氧化膦的合成；（4）目标化合物(2,4,5)-三甲氧基苯甲酰基二苯基氧化膦的光稳定性及光固化性能研究。
要求：（1）掌握有机合成的基本方法；（2）掌握无机制备的基本方法；（3）学习化合物主要的表征方法；（4）了解涂料光引发剂的相关知识，学会涂料固化的评价方法。
3. 参考文献
[1] J.-P. Fouassier, J. Laleve, Photoinitiators for Polymer Synthesis-Scope, Reactivity, and Efficiency, Wiley-VCH Verlag GmbH , Avci D. et.al. Synthesis, photophysical and photochemical Studies of benzophenone based novel monomeric and polymeric photoinitiators. Progress in Organic Coatings, 2015, 78: 200207. [4] Crivello J V. Photoinitiated cationic polymerization. Annu. Rev. Mater. Sci. 1983, 13: 173-190. [5] C. Schmitz, B. Strehmel. NIR LEDs and NIR lasers as feasible alternatives to replace oven processes for treatment of thermal-responsive coatings[J]. J. Coat. Technol. Res., 2019, 16: 15271541. [6] K. D. Belfied, J. V. Crivello, Photoinitiated Polymerization. ACS Symposium Series 847, American Chemical Society, Washington DC 2003.[7] N. S. Allen, Photochemistry and Photophysics of Polymer Materials, Wiley, USA 2010.[8] D.C. Aduba Jr., E.D. Margaretta, A.E.C. Marnot, K.V. Heifferon, W.R. Surbey, N.A. Chartrain, A.R. Whittington, T.E. Long, C.B. Williams. Vat photopolymerization 3D printing of acid-cleavable PEG-methacrylate networks for biomaterial applications[J]. Mater. Today Commun., 2019, 19: 204211.[9] S. C. Ligon-Auer, M. Schwentenwein, C. Gorsche, J. Stampfl, R. Liska, Polym. Chem. 2016, 7, 257.[10] Elodie Sprick, Jean-Michel Becht, et al. New hydrogen donors for amine-free photoinitiating systems in dental materials[J]. Dental materials, 2021, 37(3): 382-390. [11] J. Zhao, J. Lalevee, H. Lu, R. MacQueen, S. H. Kable, T. W. Schmidt, M. H. Stenzel, P. Xiao, Polym. Chem. 2015, 6, 5053.[12] J. Lalevee, J. P. Fouassier, Dyes and Chomophores in Polymer Science, ISTE Wiley, London 2015.[13] P. Xiao, J. Zhang, F. Dumur, M. A. Tehfe, F. Morlet-Savary, B. Graff, D. Gigmes, J. P. Fouassier, J. Laleve, Prog. Polym. Sci.2015, 41, 32.[14] S. Dadashi-Silab, C. Aydogan, Y. Yagci, Polym. Chem.2015, 6, 6595.[15] J. Radebner, A. Eibel, M. Leypold, C. Gorsche, L. Schuh, R. Fischer, A. Torvisco, D. Neshchadin, R. Geier, N. Moszner, R. Liska, G. Gescheidt, M. Haas, H. Stueger, Angew. Chem., Int. Ed.2017, 56, 3103.[16] M. Jin, X. Wu, J. P. Malval, D. Wan, H. Pu, J. Polym. Sci. Polym. Chem. 2016, 54, 2722.[17] M. Jin, M. Yu, Y. Zhang, D. Wan, H. Pu, J. Polym. Sci. Polym. Chem.2016, 54, 1945.[18] X. Wu, J.-p. Malval, D. Wan, M. Jin, Dyes Pigm.2016, 132, 128.[19] J. Zhang, J. Lalevee, J. Zhao, B. Graff, M. H. Stenzel, P. Xiao, Polym. Chem.2016, 7, 7316.[20] P. Xiao, F. Dumur, B. Graff, J. P. Fouassier, D. Gigmes, J. Laleve, Macromolecules2013, 46, 6744.[21] J. Zhang, F. Dumur, M. Bouzrati, P. Xiao, C. Dietlin, F. MorletSavary, B. Graff, D. Gigmes, J. P. Fouassier, J. Laleve, J. Polym. Sci., Part A: Polym. Chem.2015, 53, 1719.[22] P. Xiao, W. Hong, Y. Li, F. Dumur, B. Graff, J. P. Fouassier, D. Gigmes, J. Laleve, Polym. Chem. 2014, 5, 2293[23] P. Xiao, M. Frigoli, F. Dumur, B. Graff, D. Gigmes, J. P. Fouassier, J. Laleve, Macromolecules 2014, 47, 106.[24] M.-A. Tehfe, F. Dumur, B. Graff, D. Gigmes, J.-P. Fouassier, J. Laleve, Macromol. Chem. Phys.2013, 214, 1052.[25] M.-A. Tehfe, J. Laleve, S. Telitel, J. Sun, J. Zhao, B. Graff, F. Morlet-Savary, J.-P. Fouassier, Polymer2012, 53, 2803.[26] Andrea C , Riccardo C , Vijay K R, Marco S, et al. Synthesis of γ-cyclodextrin substituted bis(acyl)phosphane oxide derivative (BAPO-γ-CyD) serving as multiple photoinitiator and crosslinking agent[J]. Chem. Commun., 2020, 56: 4828-4831.[27] P. Ghosh, G. P. Devi, R. Priya, A. Amrita, A. Sivaramakrishna, S. Babu, R. Siva, Appl. Biochem. Biotechnol.2013, 170, 1127.[28] D. Gupta, S. Kumari, M. Gulrajani, Color. Technol.2001, 117, 328.[29] F. G. Sanchez, C. C. Blanco, A. H. Bayona, Talanta 1987, 34, 345.[30] G. Cozza, M. Mazzorana, E. Papinutto, J. Bain, M. Elliott, G. di Maira, A. Gianoncelli, M. A. Pagano, S. Sarno, M. Ruzzene, R. Battistutta, F. Meggio, S. Moro, G. Zagotto, L. A. Pinna, Biochem. J.2009, 421, 387.[31] S. Markovi, J. Toovi, J. Phys. Chem. A2015, 119, 9352.[32] D. Rehm, A. Weller, Isr. J. Chem.1970, 8, 259.[33] M. A. Tehfe, J. Laleve, F. Morlet-Savary, B. Graff, N. Blanchard, J. P. Fouassier, ACS Macro Lett.2012, 1, 198.[34] P. Xiao, F. Dumur, J. Zhang, D. Gigmes, J. P. Fouassier, J. Lalevee, Polym. Chem. 2014, 5, 6350.[35] M. A. Tehfe, J. Laleve, S. Telitel, E. Contal, F. Dumur, D. Gigmes, D. Bertin, M. Nechab, B. Graff, F. Morlet-Savary, J. P. Fouassier, Macromolecules2012, 45, 4454.[36] J. Laleve, N. Blanchard, M. A. Tehfe, F. Morlet-Savary, J. P. Fouassier, Macromolecules 2010, 43, 10191.[37] Liu YY, Wang TT, Xie CB, Tian XJ, Song L, Liu L, Wang ZW, Yu Q. Naphthyl-based acylphosphine oxide photoinitiators with high effiency and low migration[J]. Prog Org Coat, 2020, 142: 105603. [38] J. Laleve, M.-A. Tehfe, A. Zein-Fakih, B. Ball, S. Telitel, F. Morlet-Savary, B. Graff, J. P. Fouassier, ACS Macro Lett.2012, 1, 802.[39] P. Xiao, F. Dumur, T. T. Bui, F. Goubard, B. Graff, F. Morlet-Savary, J. P. Fouassier, D. Gigmes, J. Laleve, ACS Macro Lett.2013, 2, 736.
4. 毕业设计（论文）计划
2021.2.25-2021.3.11 要完成这方面的文献资料查阅，写好开题报告，并完成一篇英文文献的翻译。
2021.3.11-2021.5.22根据文献，设计合成路线，合成（2,4,5-三甲氧基苯甲酰基）-二苯基氧化膦，并做相关表征。
2021.5.23-2021.6. 3 完成毕业论文的撰写及答辩。
以上是毕业论文任务书，课题毕业论文、开题报告、外文翻译、程序设计、图纸设计等资料可联系客服协助查找。
