全文总字数：4294字
1. 毕业设计（论文）的内容和要求
1. 查阅文献，了解研究课题及相关研究进展，完成开题报告。
2. 开展课题实验，掌握相关实验操作技能和材料表征方法，收集并尝试分析实验数据。
3. 整理数据，撰写论文，了解科技论文的语言表达方式。
2. 实验内容和要求
本课题研究主要是通过在MOF孔道中掺杂功能性组分（金属盐或离子液）来调控MOF材料的水蒸气吸附行为。
具体内容及要求如下：1） 以MIL-101(Cr)为例，合成MOF材料并在其孔道中掺杂功能性组分。
掌握材料合成和表征方法以及相关的实验技能；2） 通过调控功能性组分在MOF中的含量，调控其水蒸气吸附性能，掌握实验方法并了解相关机理。
3. 参考文献
1. Bahadori, M.;Marandi, A.;Tangestaninejad, S.;Moghadam, M.;Mirkhani, V.; Mohammadpoor-Baltork, I., Ionic Liquid-Decorated MIL-101(Cr) via Covalent and Coordination Bonds for Efficient Solvent-Free CO2 Conversion and CO2 Capture at Low Pressure. J Phys Chem C 2020, 124 (16), 8716-8725.2. Bolne, P. C.;Ghodke, S. A.; Bhanvase, B. A., Intensified Hydrodynamic Cavitation-Based Process for the Production of Liquid Emulsion Membrane (LEM) for the Extraction of Chromium(VI) Ions. Int J Environ Res 2021.3. Elsayed, E.;Al-Dadah, R.;Mahmoud, S.;Anderson, P. A.;Elsayed, A.; Youssef, P. G., CPO-27(Ni), aluminium fumarate and MIL-101(Cr) MOF materials for adsorption water desalination. Desalination 2017, 406, 25-36.4. Elsayed, E.;Anderson, P.;AL-Dadah, R.;Mahmoud, S.; Elsayed, A., MIL-101(Cr)/calcium chloride composites for enhanced adsorption cooling and water desalination. J Solid State Chem 2019, 277, 123-132.5. Furukawa, S.;Reboul, J.;Diring, S.;Sumida, K.; Kitagawa, S., Structuring of metal-organic frameworks at the mesoscopic/macroscopic scale. Chem Soc Rev 2014, 43 (16), 5700-5734.6. Kalmutzki, M. J.;Diercks, C. S.; Yaghi, O. M., Metal-Organic Frameworks for Water Harvesting from Air. Adv Mater 2018, 30 (37).7. Karimi, D.;Behi, H.;Hosen, M. S.;Jaguemont, J.;Berecibar, M.; Van Mierlo, J., A compact and optimized liquid-cooled thermal management system for high power lithium-ion capacitors. Appl Therm Eng 2021, 185.8. Maurya, A.; Haldar, C., Liquid-phase oxidation of olefins with rare hydronium ion salt of dinuclear dioxido-vanadium(V) complexes and comparative catalytic studies with analogous copper complexes. Appl Organomet Chem 2021.9. Sun, P.;Huang, K.; Liu, H. Z., Competitive Adsorption of Ions at the Oil-Water Interface: A Possible Mechanism Underlying the Separation Selectivity for Liquid-Liquid Solvent Extraction. Langmuir 2018, 34 (44), 13155-13161.10. Tan, B. Q.;Luo, Y. S.;Liang, X. H.;Wang, S. F.;Gao, X. N.;Zhang, Z. G.; Fang, Y. T., Composite salt in MIL-101(Cr) with high water uptake and fast adsorption kinetics for adsorption heat pumps. Micropor Mesopor Mat 2019, 286, 141-148.11. Tan, B. Q.;Luo, Y. S.;Liang, X. H.;Wang, S. F.;Gao, X. N.;Zhang, Z. G.; Fang, Y. T., Mixed-Solvothermal Synthesis of MIL-101(Cr) and Its Water Adsorption/Desorption Performance. Ind Eng Chem Res 2019, 58 (8), 2983-2990.12. Teo, H. W. B.;Chakraborty, A.; Kayal, S., Post synthetic modification of MIL-101(Cr) for S-shaped isotherms and fast kinetics with water adsorption. Appl Therm Eng 2017, 120, 453-462.13. Wang, Z. T.;Zhou, H.;Meng, C. F.;Xiong, W. W.;Cai, Y. J.;Hu, P. F.;Pang, H.; Yuan, A. H., Enhancing Ion Transport: Function of Ionic Liquid Decorated MOFs in Polymer Electrolytes for All-Solid-State Lithium Batteries. Acs Appl Energ Mater 2020, 3 (5), 4265-4274.14. Wankowski, J. L.; Dietz, M. L., Ionic liquid (IL) cation and anion structural effects on the extraction of metal ions into N-alkylpyridinium-based ILs by a macrocyclic polyether. Solvent Extr Ion Exc 2021, 39 (2), 233-253.15. Xu, J. X.;Li, T. X.;Chao, J. W.;Wu, S.;Yan, T. S.;Li, W. H.;Cao, B. Y.; Wang, R. H., Efficient Solar-Driven Water Harvesting from Arid Air with Metal-Organic Frameworks Modified by Hygroscopic Salt. Angew Chem Int Edit 2020, 59 (13), 5202-5210.16. Xu, W. T.; Yaghi, O. M., Metal-Organic Frameworks for Water Harvesting from Air, Anywhere, Anytime. Acs Central Sci 2020, 6 (8), 1348-1354.17. Yaghi, O., Metal-organic frameworks for practical water harvesting from desert air. Abstr Pap Am Chem S 2019, 258.18. 李建惠，兰天昊，陈杨. MOF复合材料在气体吸附分离中的研究进展[J].化工学报，2021年1期19. 李宝霖，叶木金.离子液体在气体吸附中的应用研究[J]. 山东化工. 2016,45(21)20. Fujie, K.; Kitagawa, H., Ionic liquid transported into metal-organic frameworks. Coordin Chem Rev 2016, 307, 382-390.
4. 毕业设计（论文）计划
2021.1.206-2021.3.13 搜集相关文献并阅读，明确实验目的，完成文献翻译及开题报告。
2021.3.14-2021.4.15 开展材料合成及表征实验。
2021.4.16-2021.6.3 收集整理并分析实验数据，完成毕业论文。
以上是毕业论文任务书，课题毕业论文、开题报告、外文翻译、程序设计、图纸设计等资料可联系客服协助查找。
