1. 毕业设计(论文)的内容和要求
本课题在理解铝电池研究背景、掌握其硫正极材料研究概况以及分析相关研究存在的问题的基础上。
制备硫基复合正极材料,结合微结构表征,分析材料的结构及物相变化;将所制备的硫基正极材料制成电极,以离子液体为电解液,金属铝为负极,组装电池,测试正极材料的电化学性能。
分析、总结数据,并撰写毕业论文。
2. 参考文献
根据毕业要求指点3.1,毕设期间要进行研究现状调查与总结,要求在开题报告及毕业设计(论文)中涉及的英文文献不少于20篇,其中近5年不少于8篇,英文文献不少于5篇。
以下是与本课题相关的部分文献列表: [1] Jayaprakash, N., Das, S.K., and Archer, L.A., The rechargeable aluminum-ion battery [J]. Chemical Communications 2011, 47(47): 12610-12612.[2] Reed, L.D., and Menke, E., The Roles of V2O5 and Stainless Steel in Rechargeable Al-Ion Batteries [J]. Journal of the Electrochemical Society 2013, 160(6): A915-A917.[3] Abbott, A.P., et al., Aluminium electrodeposition under ambient conditions [J]. Physical Chemistry Chemical Physics 2014, 16: 14675-14681.[4] Kitada, A., et al., AlCl3-dissolved Diglyme as Electrolyte for Room-Temperature Aluminum Electrodeposition [J]. Electrochemistry 2014, 82(11): 946-948.[5] Chiku, M., et al., Amorphous Vanadium Oxide/Carbon Composite Positive Electrode for Rechargeable Aluminum Battery. ACS Applied Materials Interfaces 2015, 7(44): 24385-24389.[6] Cohn, G., Ma, L., and Archer, L.A., A novel non-aqueous aluminum sulfur battery [J]. Journal of Power Sources 2015, 283: 416-422.[7] Geng, L.X., et al., Reversible Electrochemical Intercalation of Aluminum in Mo6S8 [J]. Chemistry of Materials 2015, 27(14): 4926-4929.[8] Li, M., et al., Electrodeposition of aluminum from AlCl3/acetamide eutectic solvent [J]. Electrochimica Acta 2015, 180: 811-814.[9] Li, Z., et al., Reversible Aluminum-Ion Intercalation in Prussian Blue Analogs and Demonstration of a High-Power Aluminum-Ion Asymmetric Capacitor [J]. Advanced Energy Materials 2015. 5(5): 1401410.[10] Lin, M.C., et al., An ultrafast rechargeable aluminium-ion battery [J]. Nature 2015, 520(7547): 324-328.[11] Nakayama, Y., et al., Sulfone-based electrolytes for aluminium rechargeable batteries [J]. Physical Chemistry Chemical Physics 2015. 17(8): p. 5758-5766.[12] Reed, L.D., et al., A rechargeable aluminum-ion battery utilizing a copper hexacyanoferrate cathode in an organic electrolyte [J]. Chemical Communications 2015, 51(76): 14397-14400.[13] Sun, H.B., et al., A new aluminium-ion battery with high voltage, high safety and low cost. Chemical Communications 2015, 51(59): 11892-11895.[14] Wang, H.L., et al., Binder-Free V2O5 Cathode for Greener Rechargeable Aluminum Battery [J]. ACS Applied MaterialsInterfaces 2015, 7(1): 80-84.[15] Gao, T., et al., A Rechargeable Al/S Battery with an Ionic-Liquid Electrolyte [J]. Angewandte Chemie International Edition 2016, 55(34): 9898-9901.[16] Gonzalez, J.R., et al., Reversible intercalation of aluminium into vanadium pentoxide xerogel for aqueous rechargeable batteries [J]. RSC Advances 2016, 6(67): 62157-62164.[17] Mori, T., et al., Discharge/charge reaction mechanisms of FeS2 cathode material for aluminum rechargeable batteries at 55 degrees C [J]. Journal of Power Sources 2016, 313: 9-14.[18] Tong, X.F., et al., Carbon-Coated Porous Aluminum Foil Anode for High-Rate, Long-Term Cycling Stability, and High Energy Density Dual-Ion Batteries [J]. Advanced Materials 2016, 28(45): 9979-9985.[19] Yang, G.Y., et al., Fabrication of tunable 3D graphene mesh network with enhanced electrical and thermal properties for high-rate aluminum-ion battery application [J]. RSC Advances, 2016, 6(53): 47655-47660.[20] Yu, Z.J., et al., Hexagonal NiS nanobelts as advanced cathode materials for rechargeable Al-ion batteries. Chemical Communications 2016, 52(68): 10427-10430.[21] Hu, Y., et al., An Innovative Freeze-Dried Reduced Graphene Oxide Supported SnS2 Cathode Active Material for Aluminum-Ion Batteries [J]. Advanced Materials 2017, 29(48): 1606132.[22] Li, J., et al., Ternary AlCl3-Urea-[EMIm]Cl Ionic Liquid Electrolyte for Rechargeable Aluminum-Ion Batteries [J]. Journal of The Electrochemical Society 2017, 164(13): A3093-A3100.[23] Stadie, N.P., et al., Zeolite-Templated Carbon as an Ordered Microporous Electrode for Aluminum Batteries [J]. ACS Nano 2017, 11(2): 1911-1919.[24] VahidMohammadi, A., et al., Two-Dimensional Vanadium Carbide (MXene) as a High-Capacity Cathode Material for Rechargeable Aluminum Batteries [J]. ACS Nano 2017, 11(11): 11135-11144.[25] Chen, C.Y., et al., Rechargeable aluminum batteries utilizing a chloroaluminate inorganic ionic liquid electrolyte [J]. Chemical Communications 2018, 54(33): 4164-4167.[26] Jiang, J., et al., One-Dimensional Cu2- xSe Nanorods as the Cathode Material for High-Performance Aluminum-Ion Battery [J]. ACS Applied Materials Interfaces 2018, 10(21): 17942-17949.[27] Yang, C., et al., Substituent Effect of Imidazolium Ionic Liquid: A Potential Strategy for High Coulombic Efficiency Al Battery [J]. Journal of Physical Chemistry C 2019, 123(18): 11522-11528.[28] Guo, Y., et al., Carbonized-MOF as a Sulfur Host for Aluminum-Sulfur Batteries with Enhanced Capacity and Cycling Life [J]. Advanced Functional Materials 2019, 29: 1807676.[29] Chu, W., et al., A low-cost deep eutectic solvent electrolyte for rechargeable aluminum-sulfur battery [J]. Energy Storage Materials 2019, 22: 418-423.[30] Kong, Y., et al. Modulating Ion Diffusivity and Electrode Conductivity of Carbon Nanotube@Mesoporous Carbon Fibers for High Performance Aluminum-Selenium Batteries [J]. Small 2019, 15: 1904310.
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