压力诱导MOFs晶形转变构建MOFs发光复合材料任务书

 2021-10-22 21:50:27

1. 毕业设计(论文)的内容和要求

传统的发光材料主要包括两大板块,即有机发光材料和无机发光材料,这两类发光材料各具自身的特点。

一般而言,与无机发光材料相比, 有机发光材料具有驱动电压低、亮度高、发光效率高以及易实现大面积彩色显示等优点,从而备受人们的关注。

然而,在实际商业化应用进程中,它又表现出光效差、寿命短及稳定性差等致命缺陷,进而影响了它的进一步商品化。

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2. 参考文献

参考文献[1] Stein A, Melde B J, Schroden R C. Hybrid inorganic-organic mesoporous silicates-nanoscopic reactors coming of age[J] . Adv. Mater., 2000, 12(19): 1403-1419.[2] Kagan C R, Mitzi D B, Dimitrakopoulos C D. Organic-inorganic hybrid materials as semiconducting channels in thin-film field-effect transistors[J] . Science, 1999, 286(5441): 945-947.[3] Jeon N J, Noh J H, Kim Y C, et al. Solvent engineering for high-performance inorganic-organic hybrid perovskite solar cells[J] . Nat. mater., 2014, 13(9): 897-903.[4] Rowsell J L C, Yaghi O M. Metal-organic frameworks: a new class of porous materials[J] . Microporous Mesoporous Mater., 2004, 73(1-2): 3-14.[5] Kiagawa S, Uemura K. Dynamic porous properties of coordination polymers inspired by hydrogen bonds[J] . Chem. Soc. Rev., 2005, 36(17): 109-119.[6] Evans O R, Lin W B. Crystal Engineering of NLO Materials Based on Metal-Organic Coordination Networks[J] . Acc. Chem. Res., 2002, 35(7): 511-522.[7] Dechambenoit P, Long J R. Microporous magnets[J] . Chem. Soc. Rev., 2011, 40(60): 3249-3265.[8] Yoon M, Srirambalaji R, Kim K. Homochiral metal-organic frameworks for asymmetric heterogeneous catalysis[J] . Chem. Rev., 2011, 112(2): 1196-1231.\[9] Reineke T M, Eddaoudi M, Yaghi O M, et al. From Condensed Lanthanide Coordination Solids to Microporous Frameworks Having Accessible Metal Sites[J] . J. Am. Chem. Soc., 1999, 121(8): 1651-1657.[10]基于金属_有机骨架的多功能发光材料的设计合成及性质研究_张姝然

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