1. 毕业设计(论文)的内容和要求
本课题将进一步探究卤素载体作用甲醛蒸汽重整制氢的机理,以Ni/MCl为例,研究Na ,Ca2 ,K 和Ba2 等载体阳离子对甲醛蒸汽重整制氢性能的影响,进而为工业应用方法提供指导。
最后把整个研究内容写成毕业论文。
毕业论文的内容和要求如下:(1)在第1章引言部分,通过文献阅读和总结分析,给出如下内容:氢气的制备方法原理和方法,氢源、催化剂的选择研究现状,现有催化剂存在的问题或不足,本课题拟开展的研究内容和预期目标。
2. 参考文献
[1]Xunwang Shi, Kaidi Zhang, Qunpeng Cheng, Guangsen Song, Guozhi Fan, Jianfen Li. Promoting hydrogen-rich syngas production through catalytic cracking of rape straw using Ni-Fe/PAC-γAl2O3 catalyst [J]. Renewable Energy, 2019, 140, 32-38. [2]Qijie Jin, Yuesong Shen, Xiujun Li, Yanwei Zeng. Resource utilization of waste de NO(x) catalyst for continuous-flow catalysis by supported metal reactors [J]. Molecular Catalysis, 2020, 480. [3]Qijie Jin, Yuesong Shen, Yi Cai, Chu, Zeng Lin, Yanwei. Resource utilization of waste V2O5-based deNOx catalysts for hydrogen production from formaldehyde and water via steam reforming [J]. Journal of hazardous materials, 2020, 381, 120934. [4]Xueying Ren, Hao Lv, Su Yang, Yingying Wang, Jinlong Li, Wei Ren, Dongdong Xu, Ben Liu. Promoting Effect of Heterostructured NiO/Ni on Pt Nanocatalysts toward Catalytic Hydrolysis of Ammonia Borane [J]. The journal of physical chemistry letters, 2019, 10(23), 7374-7382. [5]Zhao K, Zhao S, Qi J, et al. Cu2O clusters grown on TiO2 nanoplates as efficient photocatalysts for hydrogen generation [J]. Inorganic Chemistry Frontiers, 2016, 3(4), 488-493.[6]Grewe T, Yang T, Tysz H, et al. Hyperbranched potassium lanthanum titanate perovskite photocatalysts for hydrogen generation [J]. Journal of Materials Chemistry A, 2016, 4(8), 2837-2841.[7]Zhang K, Wang L, Kim J K, et al. An order/disorder/water junction system for highly efficient co-catalyst-free photocatalytic hydrogen generation [J]. Energy reforming with methane for production of hydrogen rich, stable syngas [J]. Journal of nanoscience and nanotechnology, 2020, 20(6), 3943-3950. [9]Chengxiong Dang, Shijie Wu, Guangxing Yang, Yonghai Cao, Hongjuan Wang, Feng Peng, Hao Yu. Syngas production by dry reforming of the mixture of glycerol and ethanol with CaCO3 [J]. Journal of Energy Chemistry, 2020, 43, 90-97. [10]Lijun Zhang, Zhenjie Yu, Jiaojiao Li, Shu Zhang, Song Hu, Jun Xiang, Yi Wang, Qing Liu, Guangzhi Hu, Xun Hu. Steam reforming of typical small organics derived from bio-oil: Correlation of their reaction behaviors with molecular structures [J]. Fuel, 2020, 259.[11] Chen, Sai, Pei, Chunlei, Gong, Jinlong. Insights into interface engineering in steam reforming reactions for hydrogen production [J]. Energy rn Solheim. Gas electrodes with nickel based current collectors for molten carbonate electrolyte thermo-electrochemical cells [J]. Journal of Energy Chemistry, 2020, 41, 34-42. [20]Shun Lu, Matthew Hummel, Zhengrong Gu,Yan Gu, Zhisheng Cen, Lin Wei, Yue Zhou, Caizhi Zhang, Chi Yang. Trash to treasure: A novel chemical route to synthesis of NiO/C for hydrogen production [J]. International Journal of Hydrogen Energy, 2019, 44(31), 16144-16153.[21]杨新春, 徐强. 含金金属纳米颗粒用于液相化学氢化物催化制氢(英文) [J]. 催化学报, 2016, 37(10), 1594-1599.[22]李林. Li 掺杂的NiO固溶体和NiO/CeO2、CeO2/NiO催化剂构效关系研究 [D]. 南昌大学, 2018. [23]李凝, 王剑锋, 马浩, 杨萍, 陈富凯. 大孔Ni/CeO2催化剂的制备、表征及应用研究 [J]. 精细石油化工, 2018, 35(05), 37-41.
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