1. 毕业设计（论文）的内容和要求
本课题组采用氢化燃烧合成法制备Mg-Al储氢合金，并通过机械球磨分别微米Ni和纳米Ni作为催化剂。
通过对比氩气保护和空气暴露样品储氢性能的变化，探究添加微米Ni和纳米Ni的Mg-Al储氢合金抗空气毒化性能。
通过该毕业论文，能够系统培养学生文献检索和阅读、实验设计和实践、设备操作、数据归纳整理、理论验证、论文撰写等能力，提高学生理论研究和实践技能及分析解决复杂问题的综合素质。
2. 参考文献
[1] M. Zhu, Y.S. Lu, L.Z. Ouyang, H. Wang, Thermodynamic Tuning of Mg-Based Hydrogen Storage Alloys: A Review, Materials, 6 (2013) 4654-4674.[2] I.P. Jain, C. Lal, A. Jain, Hydrogen storage in Mg: A most promising material, International Journal of Hydrogen Energy, 35 (2010) 5133-5144.[3] X.T. Huang, A.P. Tao, J. Guo, W.L. Wei, J. Guo, Z.Q. Lan, Synergistic effect of TiF3@ graphene on the hydrogen storage properties of Mg-Al alloy, International Journal of Hydrogen Energy, 43 (2018) 1651-1657.[4] Z.Q. Lan, Z.Z. Sun, Y.C. Ding, H. Ning, W.L. Wei, J. Guo, Catalytic action of Y2O3@graphene nanocomposites on the hydrogen-storage properties of Mg-Al alloys, Journal of Materials Chemistry A, 5 (2017) 15200-15207.[5] H.Y. Shao, G.B. Xin, J. Zheng, X.G. Li, E. Akiba, Nanotechnology in Mg-based materials for hydrogen storage, Nano Energy, 1 (2012) 590-601.[6] L.G. Hou, B.C. Li, R.Z. Wu, L. Cui, P. Ji, R.Y. Long, J.H. Zhang, X.L. Li, A.P. Dong, B.D. Sun, Microstructure and mechanical properties at elevated temperature of Mg-Al-Ni alloys prepared through powder metallurgy, Journal of Materials Science 10) surface, Applied Surface Science, 464 (2019) 644-650.[17] S.D. House, J.J. Vajo, C. Ren, A.A. Rockett, I.M. Robertson, Effect of ball-milling duration and dehydrogenation on the morphology, microstructure and catalyst dispersion in Ni-catalyzed MgH2 hydrogen storage materials, Acta Materialia, 86 (2015) 55-68.[18] S.C. Luo, H.H. Han, H.X. Huang, J.G. Zhang, Y.N. Liu, Y.F. Zhu, Y. Zhang, B. Xu, L.Q. Li, Effect of Al* generated in situ in hydriding on the dehydriding properties of Mg-Al alloys prepared by hydriding combustion synthesis and mechanical milling, Journal of Alloys and Compounds, 750 (2018) 490-498.[19] S.L. Lee, C.W. Hsu, F.K. Hsu, C.-. Chou, C.K. Lin, C.W. Weng, Effects of Ni addition on hydrogen storage properties of Mg17Al12 alloy, Materials Chemistry and Physics, 126 (2011) 319-324.[20] G.W. Zhan, H.C. Zeng, Hydrogen spillover through Matryoshka-type (ZIFs@)n-1ZIFs nanocubes, Nature Communications, 9 (2018) 3778.
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