1. 毕业设计（论文）的内容和要求
本课题旨在催化改性镁基材料的储氢性能。
基于过渡金属优异的催化性能以及Ti3C2特殊的片层结构，通过静电作用将镍铁水滑石和Ti3C2进行复合，并以此为前驱体制备Ti3C2纳米片负载Ni3Fe团簇的复合型催化剂。
此种形貌可以有效抑制Ti3C2的堆叠，且此种多相催化成分对氢化镁的储氢性能具有协同作用。
2. 参考文献
根据毕业要求指点10.2，毕设期间要进行研究现状调查与总结，要求在开题报告及毕业设计（论文）中涉及的英文文献不少于20篇，其中近5年不少于8篇，英文文献不少于5篇。
以下是与本课题相关的部分文献列表： [1] He T, Pachfule P, Wu H, Xu Q, Chen P. Hydrogen carriers. Nat Rev Mater 2016;1:16059.[2] Mohtadi R, Orimo S-i. The renaissance of hydrides as energy materials. Nat Rev Mater 2016;2:16091.[3] Yartys VA, Lototskyy MV, Akiba E, Albert R, Antonov VE, Ares JR, et al. Magnesium based materials for hydrogen based energy storage: Past, present and future. Int J Hydrogen Energy 2019;44:7809-59.[4] Liu YF, Zhong K, Luo K, Gao MX, Pan HG, Wang QD. Size-dependent kinetic enhancement in hydrogen absorption and desorption of the Li-Mg-N-H system. J Am Chem Soc 2009;131:1862-70.[5] Shao HY, He LQ, Lin HJ, Li H-W. Progress and trends in magnesium-based materials for energy-storage research: A review. Energy Technol 2018;6:445-58.[6] Jain P, Dixit V, Jain A, Srivastava ON, Huot J. Effect of magnesium fluoride on hydrogenation properties of magnesium hydride. Energies 2015;8:12546-56.[7] Cui J, Wang H, Liu JW, Ouyang LZ, Zhang QG, Sun DL, et al. Remarkable enhancement in dehydrogenation of MgH2 by a nano-coating of multi-valence Ti-based catalysts. J Mater Chem A 2013;1:5603-11.[8] Liu YF, Du HF, Zhang X, Yang YX, Gao MX, Pan HG. Superior catalytic activity derived from a two-dimensional Ti3C2 precursor towards the hydrogen storage reaction of magnesium hydride. Chem Commu 2016;52:705-8.[9] Si TZ, Ma Y, Li YT, Liu DM. Solid solution of Cu in Mg2NiH4 and its destabilized effect on hydrogen desorption. Mater Chem Phys 2017;193:1-6.[10] Cho ES, Ruminski AM, Aloni S, Liu YS, Guo JH, Urban JJ. Graphene oxide/metal nanocrystal multilaminates as the atomic limit for safe and selective hydrogen storage. Nat Commun 2016;7:7.[11] Zhang JG, Zhu YF, Lin HJ, Liu YN, Zhang Y, Li SY, et al. Metal hydride nanoparticles with ultrahigh structural stability and hydrogen storage activity derived from microencapsulated nanoconfinement. Adv Mater 2017;29:1700760.[12] Sun YH, Ma TY, Aguey-Zinsou K-F. Magnesium supported on nickel nanobelts for hydrogen storage: coupling nanosizing and catalysis. ACS Appl Nano Mater 2018;1:1272-9.[13] Edalati K, Kitabayashi K, Ikeda Y, Matsuda J, Li HW, Tanaka I, et al. Bulk nanocrystalline gamma magnesium hydride with low dehydrogenation temperature stabilized by plastic straining via high-pressure torsion. Scr Mater 2018;157:54-7.[14] Qun L, Gu QF, Liu B, Zhang T-F, Liu WQ, Li Q. Achieving superior cycling stability by in-situ forming NdH2-Mg-Mg2Ni nanocomposites. J Mater Chem A 2018;6:23308-17.[15] Lin HJ, Ouyang LZ, Wang H, Zhao DQ, Wang WH, Sun DL, et al. Hydrogen storage properties of Mg-Ce-Ni nanocomposite induced from amorphous precursor with the highest Mg content. Int J Hydrogen Energy 2012;37:14329-35.[16] Li JS, Xie LS, Zhang TB, Song L. Microstructure and absorption/desorption kinetics evolutions of Mg Ni Ce alloys during hydrogenation and dehydrogenation cycles. Int J Hydrogen Energy 2018;43:8404-14.[17] Xie L, Liu Y, Zhang XZ, Qu JL, Wang YT, Li XG. Catalytic effect of Ni nanoparticles on the desorption kinetics of MgH2 nanoparticles. J Alloys Compd 2009;482:388-92.[18] Wu CZ, Wang YL, Liu Y, Ding WZ, Sun CH. Enhancement of hydrogen storage properties by in situ formed LaH3 and Mg2NiH4 during milling MgH2 with porous LaNiO3. Catal Today 2017;318:113-8.[19] Leng HY, Pan YB, Li Q, Chou KC. Effect of LiH on hydrogen storage property of MgH2. Int J Hydrogen Energy 2014;39:13622-7.[20] House SD, Vajo JJ, Ren C, Rockett AA, Robertson IM. Effect of ball-milling duration and dehydrogenation on the morphology, microstructure and catalyst dispersion in Ni-catalyzed MgH2 hydrogen storage materials. Acta Mater 2015;86:55-68.[21] Wang ZY, Ren ZH, Jian N, Gao MX, Hu JJ, Du F, et al. Vanadium oxide nanoparticles supported on cubic carbon nanoboxes as highly active catalyst precursors for hydrogen storage in MgH2. J Mater Chem A 2018;6:16177-85.[22] Lang CG, Ouyang LZ, Yang LL, Dai LY, Wu DF, Shao HY, et al. Enhanced hydrogen storage kinetics in Mg@FLG composite synthesized by plasma assisted milling. Int J Hydrogen Energy 2018;43:17346-52.
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