1. 毕业设计（论文）的内容和要求
本课题旨在利用水热法和煅烧法，将α-MnO2与Co3O4复合制备α-MnO2/Co3O4复合催化剂。
比较α-MnO2/Co3O4复合催化剂和单组份α-MnO2、Co3O4之间的微观结构和ORR/OER催化活性差异。
将所制备催化剂应用在扣式铝-空气电池中探究α-MnO2/Co3O4复合催化剂和单组份α-MnO2、Co3O4催化剂对电池循环充放电性能的影响。
2. 参考文献
根据毕业要求指点2.3，毕设期间要进行研究现状调查与总结，要求在开题报告及毕业设计（论文）中涉及的英文文献不少于20篇，其中近5年不少于8篇，英文文献不少于5篇。
以下是与本课题相关的部分文献列表：[1] J. Ryu, M. Park, J. Cho, Advanced technologies for high-energy aluminum-air batteries, Adv. Mater. 31 (2019) 1804784.[2] M.A. Rahman, X.J. Wang, C.E. Wen, High energy density metal-air batteries: A review, J. Electrochem. Soc. 160 (2013) A1759-A1771.[3] Q.X. Kang, Y. Wang, X.Y. Zhang, Experimental and theoretical investigation on calcium oxide and L-aspartic as an effective hybrid inhibitor for aluminum-air batteries, J. Alloys Compd. 774 (2019) 1069-1080.[4] B.J. Hopkins, Y.S. Horn, D.P. Hart, Suppressing corrosion in primary aluminumair batteries via oil displacement, Science 362 (2018) 658-661.[5] J.M. Ren, J.B. Ma, J. Zhang, C.P. Fu, B.D. Sun, Electrochemical performance of pure Al, AlSn, AlMg and AlMgSn anodes for Al-air batteries, J. Alloys Compd. 808 (2019) 151708.[6] H. Liu, H.J. Yu, Ionic liquids for electrochemical energy storage devices applications, J. Mater. Sci. Technol. 35 (2019) 674-686.[7] N. Bogolowski, J.F. Drillet, An electrically rechargeable Al-air battery with aprotic ionic liquid electrolyte, ECS Trans. 75 (2017) 85-92.[8] M. Kar, T.J. Simons, M. Forsyth, D.R. MacFarlane, Ionic liquid electrolytes as a platform for rechargeable metal-air batteries: a perspective, Phys. Chem. Chem. Phys. 16 (2014) 18658-18674.[9] R. Revel, T. Audichon, S. Gonzalez, Non-aqueous aluminiumair battery based on ionic liquid electrolyte, J. Power Sources 272 (2014) 415-421.[10] D. Gelman, B. Shvartsev, Y. Ein-Eli, Aluminumair battery based on an ionic liquid electrolyte, J. Mater. Chem. A 2 (2014) 20237-20242.[11] M. Mokhtar, M.Z.M. Talib, E.H. Majlan, S.M. Tasirin, W.M.F.W. Ramli, W.R.W. Daud, J. Sahari, Recent developments in materials for aluminumair batteries: A review, J. Ind. Eng. Chem. 32 (2015) 1-20.[12] D.R. Egan, C.P.d. Len, R.J.K. Wood, R.L. Jones, K.R. Stokes, F.C. Walsh, Developments in electrode materials and electrolytes for aluminiumair batteries, J. Power Sources 236 (2013) 293-310.[13] N. Bogolowski, J.F. Drillets, Activity of different AlCl3-based electrolytes for the electrically rechargeable aluminium-air battery, Electrochimica Acta 274 (2018) 353-358.[14] R. Mori, Suppression of byproduct accumulation in rechargeable aluminumair batteries using non-oxide ceramic materials as air cathode materials, Sustainable Energ. Fuels 1 (2017) 1082-1089.[15] R. Mori, Electrochemical properties of a rechargeable aluminumair battery with a metalorganic framework as air cathode material, RSC Adv. 7 (2017) 6389-6395.[16] H. Jiang, J.X. Gu, X.S. Zheng, M. Liu, X.Q. Qiu, L.B. Wang, W.Z. Li, Z.F. Chen, X.B. Ji, J. Li, Defect-rich and ultrathin N doped carbon nanosheets as advanced trifunctional metal-free electrocatalysts for the ORR, OER and HER, Energ. Environ. Sci. 12 (2019) 322-333.[17] F.Y. Cheng, J. Chen, Metal-air batteries: from oxygen reduction electrochemistry to cathode catalysts, Chem. Soc. Rev. 41 (2012) 2172-2192.[18] D.U. Lee, P. Xu, Z.P. Cano, A.G. Kashkooli, M.G. Park, Z.W. Chen, Recent progress and perspectives on bi-functional oxygen electrocatalysts for advanced rechargeable metalair batteries, J. Mater. Chem. A 4 (2016) 7107-7134.[19] B.B. Xu, H. Lu, W. Cai, Y. Cao, Y. Deng, W.W. Yang, Synergistically enhanced oxygen reduction reaction composites of specific surface area and manganese valence controlled α-MnO2 nanotube decorated by silver nanoparticles in Al-air batteries, Electrochimica Acta 305 (2019) 360-369.[20] X. Gao, X. Qin, Non-aqueous rechargeable AlO2 battery with a bifunctional catalyst of carbon microspheres, Fuller. Nanotub. Car. N. 26 (2018) 111-115.
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