1. 毕业设计(论文)的内容和要求
本课题的目的是开发设计出一种MoSe2@Mxene复合电极,从而提高Li-S电池的性能。
课题基于开发高性能锂硫电池的目的,探究材料制备影响因素,研究材料形貌、结构与电化学性能之间的关系,实现对电极材料的可控制备,以提升其电化学性能。
最后把整个研究内容写成毕业论文。
2. 参考文献
根据毕业要求指点10.3,毕设期间要进行研究现状调查与总结,要求在开题报告及毕业设计(论文)中涉及的英文文献不少于20篇,其中近5年不少于8篇,英文文献不少于5篇。
以下是与本课题相关的部分文献列表:[1] Yang C P,Yin Y X,Guo Y G. Elemental Selenium for Electrochemical Energy Storage[J].Journal of Physical Chemistry Letters, 2015, 6(2): 256-266.[2] Zou K Y,Liu Y C,Jiang Y F,et al. Benzoate Acid-Dependent Lattice Dimension of Co-MOFs and MOF-Derived CoS2@CNTs with Tun able Pore Diameters for Supercapacitors[J]. Inorganic Chemistry, 2017,56(11): 6184-6196.[3] Li Z,Zhang J,Guan B Y,et al. Mesoporous Carbon@Titanium Nitride Hollow Spheres as an Efficient SeS2 Host for Advanced Li-SeS2 Batteries[J]. Angew Chem Int Ed Engl, 2017, 56(50): 16003-16007.[4] Li Z,Zhang J,Wu H B,et al. An Improved Li-SeS2 Battery with High Energy Density and Long Cycle Life[J]. Advanced Energy Materials, 2017, 7(15): 1700281.[5] Chai Z S,Zhang N N,Sun P,et al. Tailorable and Wearable Textile Devices for Solar Energy Harvesting and Simultaneous Storage[J].Acs Nano, 2016, 10(10): 9201-9207.[6] Fang Y S,Ding K,Wu Z C,et al. Architectural Engineering of Nanowire Network Fine Pattern for 30 mu m Wide Flexible Quantum Dot Light-Emitting Diode Application[J]. Acs Nano, 2016, 10(11): 10023-10030.[7] Nazar M F,Khan A M,Shah S S. Microemulsion System with Improved Loading of Piroxicam: A Study of Microstructure[J]. Aaps Pharmsc itech, 2009, 10(4): 1286-1294.[8] Wang C H,Shih H C,Tsai Y T,et al. High methanol oxidation activity of electrocatalysts supported by directly grown nitrogen-containing carbon nanotubes on carbon cloth [J]. Electrochimica Acta, 2006, 52(4): 1612-1617.[9] Chen L H,Wang Z,Lu X C,et al. Study of reversible electrode processes with unsymmetrical cyclic reciprocal derivative chronopoten tiometry[J]. Electrochimica Acta, 2006, 51(25): 5548-5555.[10] Chen L,Guo M,Zhang H F,et al. Characterization and electrocatalytic properties of PtRu/C catalysts prepared by impregnation-reduction method using Nd2O3 as dispersing reagent[J]. Electrochimica Act a, 2006, 52(3): 1191-1198.[11] Hu F P,Chen C L,Wang Z Y,et al. Mechanistic study of ethanol oxidation on Pd-NiO/C electrocatalyst[J]. Electrochimica Acta, 2006, 52(3): 1087-1091.[12] Fang R,Zhao S,Sun Z,et al. More Reliable Lithium-Sulfur Batteries: Status, Solutions and Prospects More Reliable Lithium-Sulfur Batteries: Status, Solutions and Prospects[J]. Adv Mater, 2017, 29(48): 106823.[13] Ma G Q,Wen Z Y,Wang Q S,et al. Enhanced cycle performance of a Li-S battery based on a protected lithium anode[J]. Journal of Materials Chemistry A, 2014, 2(45): 19355-19359.[14] Ma G Q,Wen Z Y,Jin J,et al. Hollow polyaniline sphere@sul fur composites for prolonged cycling stability of lithium-sulfur batteries[J]. Journal of Materials Chemistry A, 2014, 2(27): 10350-10354.[15] Ma R,Zhou Y,Chen Y,et al. Ultrafine Molybdenum Carbide Nanoparticles Composited with Carbon as a Highly Active Hydrogen-Evolution Electrocatalyst[J]. Angew Chem Int Ed Engl, 2015, 54(49): 14723-14727.[16] He J,Lv W,Chen Y,et al. Direct impregnation of SeS2 into a MOF-derived 3D nanoporous CoNC architecture towards superior rechargeable lithium batteries[J]. Journal of Materials Chemistry A, 2018,6(22): 10466-10473.[17] Zhang J,Li Z,Lou X W D. A Freestanding Selenium Disulfide Cathode Based on Cobalt Disulfide-Decorated Multichannel Carbon Fibers with Enhanced Lithium Storage Performance [J]. Angew Chem Int Ed Engl, 2017, 56(45): 14107-14112.[18] Liu C,Huang X,Wang J,et al. Hollow Mesoporous Carbon Nanocubes: Rigid-Interface-Induced Outward Contraction of Metal-Organic Frameworks [J]. Advanced Functional Materials, 2018, 28(6): 1705253.[19] Shen K,Mei H,Li B,et al. 3D Printing Sulfur Copolymer-Graphene Architectures for Li-S Batteries[J]. Advanced Energy Materials, 2018, 8(4): 1701527.[20] Ji X L,Evers S,Black R,et al. Stabilizing lithium-sulphur cathodes using polysulphide reservoirs[J]. Nature Communications, 2011, 2:325.
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