1. 毕业设计(论文)的内容和要求
本课题围绕全无机CsPbBr3钙钛矿纳米晶的可控合成及其光谱调控展开研究。
采用微反应器法,研究前驱体比例、表面活化剂的用量和比例、注射速率以及反应物浓度等合成条件对量子点合成与发光性能的影响。
最后把整个研究内容写成毕业论文。
2. 参考文献
根据毕业要求指点10.1,毕设期间要进行研究现状调查与总结,要求在开题报告及毕业设计(论文)中涉及的英文文献不少于30篇,其中英文文献不少于5篇,1篇英文文献要翻译为中文。
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Scarpellini, A. Petrozza, M. Prato, L. Manna, Tuning the Optical Properties of Cesium Lead Halide Perovskite Nanocrystals by Anion Exchange Reactions, Journal of the American Chemical Society 137 (32) (2015) 10276-10281.[11] X. Li, Y. Wu, S. Zhang, B. Cai, Y. Gu, J. Song, H. Zeng, CsPbX3 Quantum Dots for Lighting and Displays: Room-Temperature Synthesis, Photoluminescence Superiorities, Underlying Origins and White Light-Emitting Diodes, Advanced Functional Materials 26 (15) (2016) 2435-2445.[12] Z. Long, H. Ren, J. Sun, J. Ouyang, N. Na, High-throughput and tunable synthesis of colloidal CsPbX3 perovskite nanocrystals in a heterogeneous system by microwave irradiation, Chemical communications 53 (71) (2017) 9914-9917.[13] Q. Pan, H. Hu, Y. Zou, M. Chen, L. Wu, D. Yang, X. Yuan, J. Fan, B. Sun, Q. 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Ginley, T. Buonassisi, Identifying defect-tolerant semiconductors with high minority-carrier lifetimes: beyond hybrid lead halide perovskites, Mrs Communications 5 (2) (2015) 265-275.[18] B.R. Sutherland, E.H. Sargent, Perovskite photonic sources, Nature Photonics 10 (5) (2016) 295-302.[19] S. Sun, D. Yuan, Y. Xu, A. Wang, Z. Deng, Ligand-Mediated Synthesis of Shape-Controlled Cesium Lead Halide Perovskite Nanocrystals via Reprecipitation Process at Room Temperature, ACS nano 10 (3) (2016) 3648-3657.[20] M. Imran, F. Di Stasio, Z. Dang, C. Canale, A.H. Khan, J. Shamsi, R. Brescia, M. Prato, L. Manna, Colloidal Synthesis of Strongly Fluorescent CsPbBr3 Nanowires with Width Tunable down to the Quantum Confinement Regime, Chemistry of materials : a publication of the American Chemical Society 28 (18) (2016) 6450-6454.[21] J. Shamsi, Z. Dang, P. Bianchini, C. Canale, F.D. Stasio, R. Brescia, M. Prato, L. Manna, Colloidal Synthesis of Quantum Confined Single Crystal CsPbBr3 Nanosheets with Lateral Size Control up to the Micrometer Range, Journal of the American Chemical Society 138 (23) (2016) 7240-7243.[22] J. Song, L. Xu, J. Li, J. Xue, Y. Dong, X. Li, H. Zeng, Monolayer and Few-Layer All-Inorganic Perovskites as a New Family of Two-Dimensional Semiconductors for Printable Optoelectronic Devices, Advanced materials 28 (24) (2016) 4861-4869.[23] Z.-J. Li, E. Hofman, A.H. Davis, M.M. Maye, W. Zheng, General Strategy for the Growth of CsPbX3 (X = Cl, Br, I) Perovskite Nanosheets from the Assembly of Nanorods, Chemistry of Materials 30 (11) (2018) 3854-3860.[24] Z.-J. Li, E. Hofman, A.H. Davis, A. Khammang, J.T. Wright, B. Dzikovski, R.W. Meulenberg, W. Zheng, Complete Dopant Substitution by Spinodal Decomposition in Mn-Doped Two-Dimensional CsPbCl3 Nanoplatelets, Chemistry of Materials 30 (18) (2018) 6400-6409.[25] Z. Du, D. Fu, T. Yang, Z. Fang, W. Liu, F. Gao, L. Wang, Z. Yang, J. Teng, H. Zhang, W. Yang, Photodetectors with ultra-high detectivity based on stabilized all-inorganic perovskite CsPb0.922Sn0.078I3 nanobelts, Journal of Materials Chemistry C 6 (23) (2018) 6287-6296.[26] Z. Liang, S. Zhao, Z. Xu, B. Qiao, P. Song, D. Gao, X. Xu, Shape-Controlled Synthesis of All-Inorganic CsPbBr3 Perovskite Nanocrystals with Bright Blue Emission, ACS applied materials interfaces 8 (42) (2016) 28824-28830.[27] P. Tyagi, S.M. Arveson, W.A. Tisdale, Colloidal Organohalide Perovskite Nanoplatelets Exhibiting Quantum Confinement, Journal of Physical Chemistry Letters 6 (10) (2015) 1911-1916.[28] A. Pan, B. He, X. Fan, Z. Liu, J.J. Urban, A.P. Alivisatos, L. He, Y. Liu, Insight into the Ligand-Mediated Synthesis of Colloidal CsPbBr3 Perovskite Nanocrystals: The Role of Organic Acid, Base, and Cesium Precursors, ACS nano 10 (8) (2016) 7943-7954.[29] D. Yang, X. Li, H. Zeng, Surface Chemistry of All Inorganic Halide Perovskite Nanocrystals: Passivation Mechanism and Stability, Advanced Materials Interfaces 5 (8) (2018).[30] J. De Roo, M. Ibanez, P. Geiregat, G. Nedelcu, W. Walravens, J. Maes, J.C. Martins, I. Van Driessche, M.V. Kovalenko, Z. Hens, Highly Dynamic Ligand Binding and Light Absorption Coefficient of Cesium Lead Bromide Perovskite Nanocrystals, ACS nano 10 (2) (2016) 2071-2081.[31] A. Pan, M.J. Jurow, F. Qiu, J. Yang, B. Ren, J.J. Urban, L. He, Y. Liu, Nanorod Suprastructures from a Ternary Graphene Oxide-Polymer-CsPbX3 Perovskite Nanocrystal Composite That Display High Environmental Stability, Nano letters 17 (11) (2017) 6759-6765.[32] H.-C. Wang, S.-Y. Lin, A.-C. Tang, B.P. Singh, H.-C. Tong, C.-Y. Chen, Y.-C. Lee, T.-L. Tsai, R.-S. Liu, Mesoporous Silica Particles Integrated with All-Inorganic CsPbBr3 Perovskite Quantum-Dot Nanocomposites (MP-PQDs) with High Stability and Wide Color Gamut Used for Backlight Display, Angewandte Chemie-International Edition 55 (28) (2016) 7924-7929.[33] D.N. Dirin, L. Protesescu, D. Trummer, I.V. Kochetygov, S. Yakunin, F. Krumeich, N.P. Stadie, M.V. Kovalenko, Harnessing Defect-Tolerance at the Nanoscale: Highly Luminescent Lead Halide Perovskite Nanocrystals in Mesoporous Silica Matrixes, Nano letters 16 (9) (2016) 5866-5874.[34] A. Loiudice, S. Saris, E. Oveisi, D.T.L. Alexander, R. Buonsanti, CsPbBr3 QD/AlOx Inorganic Nanocomposites with Exceptional Stability in Water, Light, and Heat, Angewandte Chemie-International Edition 56 (36) (2017) 10696-10701.[35] 李乐梅, 荧光探针的制备、性能研究及其在环境化学中的应用, in, 2010.
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