1. 毕业设计（论文）的内容和要求
本课题将通过新型活性自由基聚合制备一种具有高效粘接性能的功能化含氟聚合物。
本课题拟采用丙烯酸为功能化单体，研究以P(VDF-co-CTFE)为大分子引发剂的接枝聚合的效果。
通过考察Photo-induced ATRP反应的动力学过程，揭示聚合机理，拓展有机催化原子转移自由基聚合在制备功能化含氟聚合物中的应用。
2. 参考文献
根据毕业要求指点10.2，毕设期间要进行研究现状调查与总结，要求在开题报告及毕业设计（论文）中涉及的英文文献不少于20篇，其中近5年不少于8篇，英文文献不少于5篇。
以下是与本课题相关的部分文献列表： [1] Chen YX, Tang X, Shu J, Wang XL, Hu WB, Shen QD. Crosslinked P(VDF-CTFE)/PS-COOH Nanocomposites for High-Energy-Density Capacitor Application[J].Journal of polymer science, Part B: polymer physics, 2016, 54: 11601169.[2] 邓素芬, 吴晓彦, 何立敏, 熊传溪, 董丽杰. 柔性高储能P(VDF-CTFE)/PA11-g-GMA聚合膜的制备与性能研究[J]. 高分子学报, 2014: 1386-1391.[3] Xie B, Zhang Q, Zhang HB, Zhang GZ, Qiu SY, Jiang SL. Largely enhanced ferroelectric and energy storage performances of P (VDF-CTFE) nanocomposites at a lower electric field using BaTiO3 nanowires by stirring hydrothermal method[J]. Ceramics International, 2016, 42: 19012-19018.[4] Xie LY, Huang XY, Yang K, Li ST, Jiang PK. "Grafting to" route to PVDF-HFP-GMA/BaTiO3 nanocomposites with high dielectric constant and high thermal conductivity for energy storage and thermal management applications[J]. Journal Of Materials Chemistry, 2014, 2: 5244-5251.[5] Lin MF, Lee PS. Formation of PVDF-g-HEMA/BaTiO3 nanocomposites via in situ nanoparticle synthesis for high performance capacitor applications[J].J. Mater. Chem. A, 2013, 1: 1445514459.[6] Wang JW, Wang Y, Wang F, Li SQ, Xiao J, Shen QD. A large enhancement in dielectric properties of poly(vinylidene fluoride) based all-organic nanocomposite[J]. Polymer, 2009, 50: 679-684.[7] Chu HY, Chao F, Wu XY, et al. Enhancing released electrical energy density of poly(vinylidene fluoride-co-trifluoroethylene)-graft-poly(methyl methacrylate) viathe pre-irradiation method[J]. Applied Surface Science, 2019, 465: 643-655.[8] 任荣，舒元宏，王国成，蒋涛. ATRP 法制备PVDF-g-PS 共聚物及其表征[J]. 胶体与聚合物，2013.[9] Lee JI, Kang HJ, Park KH, et al. Amphiphilic Graft Copolymers as a Versatile Binder for Various Electrodes of High-Performance Lithium-Ion Batteries[J]. small, 2016, 12: 3119-3127.[10] Tan SB, Xiong J, Zhao YF, Liu JJ, Zhang ZC. Synthesis of poly(vinylidene fluoride-cochlorotrifluoroethylene)-g-poly(methylmethacrylate) with low dielectric loss by photo-induced metal-free ATRP[J]. J. Mater. Chem. C, 2018, 6: 4131-4139.
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