氯氧化铁/多孔碳泡沫复合材料储氯性能的研究任务书

 2021-10-21 17:18:28

1. 毕业设计(论文)的内容和要求

本课题以已有的氯氧化铁作为氯离子电池正极材料的研究为基础,针对其充放电过程中存在的体积变化问题,结合纳米限域和低温热分解法制备多孔碳泡沫/氯氧化铁复合材料,希望可以改善电极材料大电流充放电能力和长程循环稳定性。

最后把整个研究内容写成毕业论文。

毕业论文的内容和要求如下:(1)在第1章引言部分,通过文献阅读和总结分析,给出如下内容:氯离子电池的原理和方法,氯离子电池的研究现状,现有氯离子电池体系存在的问题或不足,本课题拟开展的研究内容和预期目标。

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2. 参考文献

[1] F. Gschwind, H. Euchner, G. Rodriguez-Garcia, Chloride ion battery review: theoretical calculations, state of the art, safety, toxicity, and an outlook towards future developments, European Journal of Inorganic Chemistry, 21 (2017) 2784-2799.[2] T. Yu, Q. Li, X. Zhao, et al., Nanoconfined iron oxychloride material as a high-performance cathode for rechargeable chloride ion batteries, Acs Energy Letters, 2 (2017) 2341-2348.[3] X. Zhao, S. Ren, M. Bruns, et al. Chloride ion battery: A new member in the rechargeable battery family. Journal of Power Sources, 245 (2014) 706-711.[4] P. Schmidt-Winkel, W.W. Lukens, P.D. Yang, et al., Microemulsion templating of siliceous mesostructured cellular foams with well-defined ultra large mesopores, Chemistry of Materials, 12 (2000) 686-696.[5] J. Lee, K. Sohn, T. Hyeon, Low-cost and facile synthesis of mesocellular carbon foams, Chemical Communications, 22 (2002) 2674-2675.[6] J. Lee, K. Sohn, T. Hyeon, Fabrication of novel mesocellular carbon foams with uniform ultralarge mesopores, Journal of the American Chemical Society, 123 (2001) 5146-5147.[7] S.S. Kim, T.J. Pinnavaia, A low cost route to hexagonal mesostructured carbon molecular sieves, Chemical Communications, 23 (2001) 2418-2419.[8] S.S. Kim, T.R. Pauly, T.J. Pinnavaia, Non-ionic surfactant assembly of ordered, very large pore molecular sieve silicas from water soluble silicates, Chemical Communications, 17 (2000) 1661-1662.[9] J. Jiang, K. Zhao, X, Xiao, et al., Synthesis and facet-dependent photoreactivity of BiOCl single-crystalline nanosheets. Journal of the American Chemical Society, 134 (2012) 4473-4476.[10] F. Gao, D. Zeng, Q. Huang, et al., Chemically bonded graphene/BiOCl nanocomposites as high-performance photocatalysts. Physical ChemistryChemical Physics, 14 (2012) 10572-10578.[11] Y. Myung, J. Choi, F. Wu, et al., Cationically substituted Bi0.7Fe0.3OCl nanosheets as Li ion battery anodes. ACS Applied Materials Interfaces, 9 (2017) 14187-14196.[12] S. H. Kim, J. K. Kang, S. G. Hwang, et al., A theoretical-study on the electoronicstructures of MOCl (M = Ti, V and Fe) and their relationship with physical-properties. Bulletin of the Korean Chemical Spciety, 16 (1995) 299-382.[13] Z. Takehara, K. Kanamura, N. Imanish, et al., The discharge characteristics of FeOCl in an aprotic organic solvent. Bulletin of the Chemical Society of Japan, 62 (1989) 3609-3613.[14] K. Kanamura, N. Imanishi, M. Fujiwara, et al., The discharge and characteristics of FeOCl modified by an organic compound. Journal of Power Sources,26(1989) 467-473.[15] M. G. Kanatzidis, H. O. Marcy, W. J. Mccarthy, et al., In situ intercalative polymerization chemistry of FeOCl. Generation and properties of novel, highly conductive inorganic/organic polymer microlaminates. Solid State lonics, 32-33 (1989): 594-608.

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