1. 毕业设计(论文)的内容和要求
本课题从研究石墨毡在水性电解液体系的氧析出电化学行为入手,采用表面修饰的方法改善石墨毡耐氧化腐蚀性能。
最后把整个研究内容写成毕业论文。
毕业论文的内容和要求如下: (1)在第1章引言部分,通过文献阅读和总结分析,给出如下内容:不同酸浓度下溶液中水的电化学分解以及氧析出反应的工作原理,现存石墨毡表面改性的研究现状,发现现有处理方法存在的问题或不足。
2. 参考文献
根据毕业要求指点10.2,毕设期间要进行研究现状调查与总结,要求在开题报告及毕业设计(论文)中涉及的英文文献不少于20篇,其中近5年不少于8篇,英文文献不少于5篇。
以下是与本课题相关的部分文献列表: 1.Jirabovornwisut, T.; Arpornwichanop, A., A review on the electrolyte imbalance in vanadium redox flow batteries . Int. J. Hydrog. Energy 2019, 44 (45), 24485-24509;2.Herranz, J.; Durst, J.; Fabbri, E.; Patru, A.; Cheng, X.; Permyakova, A. A.; Schmidt, T. J., Interfacial effects on the catalysis of the hydrogen evolution, oxygen evolution and CO2-reduction reactions for (co-)electrolyzer development. Nano Energy 2016, 29, 4-28.3. Nourani, M.; Zackin, B. I.; Sabarirajan, D. C.; Taspinar, R.; Artyushkova, K.; Liu, F. Q.; Zenyuk, I. V.; Agar, E., Impact of Corrosion Conditions on Carbon Paper Electrode Morphology and the Performance of a Vanadium Redox Flow Battery. J. Electrochem. Soc. 2019, 166 (2), A353-A363.4. Su, X.; Yang, L.; Zhou, Y.; Lin, Y.; Yu, S., Developments of electrodes for vanadium redox flow battery. Energy Storage Science and Technology 2019, 8 (1), 65-74.5. Cecchetti, M.; Messaggi, M.; Donazzi, A.; Facibeni, A.; Russo, V.; Casari, C. S.; Li Bassi, A.; Casalegno, A.; Zago, M., A combined morphological and electrochemical characterization of carbon electrodes in vanadium redox flow batteries: Insights into positive and negative electrode performance. Electrochim. Acta 2020, 329, 10.6. Xiang, Y.; Daoud, W. A., Binary NiCoO2-modified graphite felt as an advanced positive electrode for vanadium redox flow batteries. J. Mater. Chem. A 2019, 7 (10), 5589-5600.7. Xiang, Y.; Daoud, W. A., Investigation of an advanced catalytic effect of cobalt oxide modification on graphite felt as the positive electrode of the vanadium redox flow battery. J. Power Sources 2019, 416, 175-183.8. Fetyan, A.; El-Nagar, G. A.; Lauermann, I.; Schnucklake, M.; Schneider, J.; Roth, C., Detrimental role of hydrogen evolution and its temperature-dependent impact on the performance of vanadium redox flow batteries. J. Energy Chem. 2019, 32, 57-62.9. Park, S.; Kim, H., Fabrication of nitrogen-doped graphite felts as positive electrodes using polypyrrole as a coating agent in vanadium redox flow batteries. J. Mater. Chem. A 2015, 3 (23), 12276-12283.10. Zhang, X. Y.; Wu, Q. X.; Lv, Y. H.; Li, Y. L.; Zhou, X. L., Binder-free carbon nano-network wrapped carbon felt with optimized heteroatom doping for vanadium redox flow batteries. J. Mater. Chem. A 2019, 7 (43), 25132-25141.11. Parasuraman, A.; Lim, T. M.; Menictas, C.; Skyllas-Kazacos, M., Review of material research and development for vanadium redox flow battery applications. Electrochim. Acta 2013, 101, 27-40.12.Jelinek, L.; Wei, Y. Z.; Kumagai, M., Electro-oxidation of concentrated Ce(III) at carbon felt anode in nitric acid media Ce. J. Rare Earths 2006, 24 (3), 257-263.13. Jiang, F. J.; He, Z. Q.; Guo, D. Y.; Zhou, X. J., Carbon aerogel modified graphite felt as advanced electrodes for vanadium redox flow batteries. J. Power Sources 2019, 440, 7.14. Huang, P.; Ling, W.; Sheng, H.; Zhou, Y.; Wu, X. P.; Zeng, X. X.; Wu, X. W.; Guo, Y. G., Heteroatom-doped electrodes for all-vanadium redox flow batteries with ultralong lifespan. J. Mater. Chem. A 2018, 6 (1), 41-44.15. Suntivich, J.; Perry, E. E.; Gasteiger, H. A.; Shao-Horn, Y., The Influence of the Cation on the Oxygen Reduction and Evolution Activities of Oxide Surfaces in Alkaline Electrolyte. Electrocatalysis 2013, 4 (1), 49-55.16. T. X. Huong Le, M. Bechelany, M. Cretin, Carbon 2017, 122, 564.17. K. J. Kim, Y.J. Kim, J.H. Kim, M.S. Park, Materials Chemistry and Physics 2011, 131,547.
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