1. 毕业设计（论文）的内容和要求
本课题采用共沉淀合成普鲁士蓝的技术，在水系电解液中搭建钾离子电池的装置，并通过研究电流、电压、电解液浓度、共沉淀合成时间以及共沉淀溶液浓度等因素，结合现代分析技术，如SEM，XRD，初步探讨合成工艺与普鲁士蓝结构和颗粒尺寸的关系。
最后把整个研究内容写成毕业论文。
毕业论文的内容和要求如下：（1）在第一章文献综述部分，通过文献阅读和总结分析，给出如下内容：水系钾离子电池的基本信息、正极材料的要求、普鲁士蓝的简介和常见的制备技术研究进展、材料的共沉淀合成技术研究进展等，本课题拟开展的研究内容和预期目标。
2. 参考文献
[1] Kim D. J, Jung Y. H, Bharathi K. K, Je S. H, Kim D. K, Coskun A, Choi J. W. An aqueous sodium ion hybid battery incorporating an organic compund and a Prussian blue derivative.[J]. Adv.Energy Mater. 2014,4,1400133.[2] Wu X. Y, Deng W. W, Qian J. F, Cao Y. L, Ai X. P, Yang H. X. Single-crystal FeFe(CN)6 nanoparticles：a high capacity and high rate cathode for Na-ion batteries. J. Mater. Chem. A.2013,1,10130-10134. [3] Lee H, Jo E, Chung K Y, et al. In-depth TEM Investigation on Structural Inhomogeneity within a Primary LixNi0.835Co0.15Al0.015O2 Particle: Origin of Capacity Decay during High-rate Discharge[J]. Angew Chem Int Ed Engl, 2019.[4] Liu C. Y, Wang X. S, Deng W. J, Li C, Chen J. T, Xue M. Q, Li R, Pan F. Engineering fast ion conduction and selective cation channels for a high-rate and high-voltage hybrid aqueous battery[J]. Angew. Chem. In. Ed.2018,57,7046-7050.[5] Mao Y, Chen Y, Qin J, et al. Capacitance controlled, hierarchical porous 3D ultra-thin carbon networks reinforced prussian blue for high performance Na-ion battery cathode[J]. Nano Energy, 2019, 58: 192-201.[6] Wong M. H, Zhang Z. X, Yang X F, Chen X. J, Ying J. Y.One-pot in situ redox synthesis of hexacyanoferrate/conductive polymer hybrids as lithium-ion battery cathodes.[J]. Chem. Commun. 2015, 51, 13674-13677. [7] Gao X, Wang B, Zhang Y, et al. Graphene-scroll-sheathed α-MnS coaxial nanocables embedded in N, S Co-doped graphene foam as 3D hierarchically ordered electrodes for enhanced lithium storage[J]. Energy Storage Materials, 2019, 16: 46-55.[8] Song J, Wang L, Lu Y. H, Liu J, Guo B. K, Xiao P. H, Lee J. J, Yang X. Q, Henkelman G, Goodenough J. B. Removal of Interstitial H2O in Hexacyanometallates for a Superior Cathode of a Sodium-lon Battery J. Amer: Chem. Soc. 2015.l37.2658-2664.[9] Wang J, Liu J, Chao D, et al. Self-Assembly of Honeycomb-like MoS2 Nanoarchitectures Anchored into Graphene Foam for Enhanced Lithium-Ion Storage[J]. Advanced Materials, 2014, 26(42): 7162-7169.[10] You Y, Yao H. R, Xin S, Yin Y. X, Zuo T. T, Yang C. P, Guo Y. G, Cui Y, Wan, L. J, Goodenough J. B. Subzero-temperature Cathode for a Sodium lon Battery. [J]. Adv Mater, 2016, 28, 7243-7248. [11] Hao J, Zheng J, Ling F, et al. Strain-engineered two-dimensional MoS2 as anode material for performance enhancement of Li/Na-ion batteries[J]. Sci Rep, 2018, 8(1): 2079.[12] Zhang L, Ji X, Ren X, et al. Electrochemical Ammonia Synthesis via Nitrogen Reduction Reaction on a MoS2 Catalyst: Theoretical and Experimental Studies[J]. Adv Mater, 2018, 30(28): e1800191.[13] You Y, Yao H R, Xin S, et al. Subzero-Temperature Cathode for a Sodium-Ion Battery[J]. Adv Mater, 2016, 28(33): 7243-8.[14] 尾妹三郎．スルァオソ酸型カチォソ交换樹脂にカリウム選択交换性を付与してイオ交换すゐ方法 [P]．JP 46-43082，1971-12-20．[15] Pasta M, Wessells C. D, Huggins R. A, Cui Y. A high-rate and long cycle life aqueous electrolyte battery for grid-scale energy storage.[J]. Nat.Commum. 2012,3,1149
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