离子交换法制备Sr/Zn-MOF-74及其碱催化性能研究任务书

 2021-10-23 21:39:46

1. 毕业设计(论文)的内容和要求

本课题以制备Zn-MOF-74为基础,通过有效策略合成Sr/Zn-MOF-74,研究其催化性能性能。

对所获得双金属MOF-74衍生物的物理化学性质进行表征,并进行相关评价。

要求:(1)具备文献检索、阅读和信息综合分析的能力。

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2. 参考文献

[1] Busca G. Bases and Basic Materials in Chemical and Environmental Processes. Liquid Versus Solid Basicity [J]. Chem. Rev., 2010,110(4): 2217-2249.[2] Sun L B,Liu X Q,Zhou H C. Design and Fabrication of Mesoporous Heterogeneous Basic Catalysts [J]. Chem. Soc. Rev.,2015,44(15): 5092-5147.[3] 李向召,江琦.固体碱催化剂研究进展[J].天然气化工,2005(01):42-48 53.[4] Zhu L, Liu X Q,Jiang H L,et al. Metal-Organic Frameworks for Heterogeneous Basic Catalysis [J]. Chem. Rev.,2017,117(12): 8129-8176.[5] Tsuji H, Okamura-Yoshida A, Shishido T, et al. Dynamic Behavior of Carbonate Species on Metal Oxide Surface: Oxygen Scrambling between Adsorbed Carbon Dioxide and Oxide Surface [J]. Langmuir, 2003, 19(21): 8793-8800.[6] Kazumasa Akutu, Hajime Kabashima, Tsunetake Seki, et al. Nitroaldol reaction over solid base catalysts. 2003, 247(1):65-74.[7] Chizallet Cline, Costentin Guylne, Che Michel, et al. Revisiting acido-basicity of the MgO surface by periodic density functional theory calculations: role of surface topology and ion coordination on water dissociation.. 2006, 110(32):15878-86.[8] Shu-Guo Wang.Amino groups immobilized on MCM-48:an efficient heterogeneous catalyst for the Knoevenagel reaction. 2003, 4(9):469-470.[9] Choudary B M, Kantam M L, Neeraja V, et al. Layered Double Hydroxide Fluoride: A Novel Solid Base Catalyst for C-C Bond Formation [J]. Green Chem., 2001, 3(5): 257-260.[10] G. Anastopoulos, G. S. Dodos, S. Kalligeros, et al. Biodiesel Production by Ethanolysis of Various Vegetable Oils Using Calcium Ethoxide as a Solid Base Catalyst. 2013, 10(5):468-481.[11] Hattori H. Solid Base Catalysts: Fundamentals and Their Applications in Organic Reactions [J]. Appl. Catal. A: Gen., 2015, 504: 103-109.

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