1. 毕业设计（论文）的内容和要求
本课题基于背包式反应精馏集成技术，以苯部分加氢获得的环己烯环己烷混合物作为原料，构建常压较高温度反应-减压较低温度精馏生产乙酸环己酯新型反应分离集成工艺，利用Aspen Plus对过程结构参数以及操作参数进行优化设计。
2. 参考文献
[1] 单祥磊. 环己烯水合制备环己醇催化反应过程的研究[D]. 上海:华东理工大学, 2011. [2] 张莹，张晓娟，唐丽华. 环己烷氧化制环己醇和环己酮技术的研究进展[J]. 广州化工，2012, 40(10): 14-16. [3] 郭治武，金海波，佟泽明. 环己酮、环己醇制备技术进展[J]. 化工进展, 2006, 25(8): 852-858. [4] Fang D R, Lu J Y, Zhang H M. Catalysts for Hydration of Cyclohexene With Zeolites[J]. Catalysis Surveys from Japan, 1997, 1(2): 241-246. [5] Yuan P Q, Liu Y, Bai F, et al. Hydration of Cyclohexene in Sub-critical Water over WOx-ZrO2 Catalysts[J]. Catalysis Communications, 2011, 12(8): 753-756. [6] 吴济民，戴新民，陈聚良. 环己烯水合反应生成环己醇工艺条件的优化[J]. 化工进展, 2003, 22(11): 1222-1224. [7] Chakrabrati A, Sharma M M. Cyclohexanol from Cyclohexene via Cyclohexyl Acetate: Catalysis by Ion-Exchange Resin and Acid-treated Clay[J]. Reactive Polymers, 1992, 18(2):107-115. [8] Steyer F, Freund H, Sundmacher K. A Novel Reactive Distillation Process for the Indirect Hydration of Cyclohexene to Cyclohexanol Using a Reactive Entrainer[J]. Industrial and Engineering Chemistry Research, 2008, 47(23): 9581-9587. [9] Zhou F, Tang J H, Fei Z Y. et al. Efficient Cyclohexyl Acrylate Production by Direct Addition of Acrylic Acid and Cyclohexene over SBA-15-SO3H[J]. Journal of Porous Materials, 2014, 21(2): 149-155. [10] 董森，彭胜，郭学华. 阳离子交换树脂催化合成乙酸环己酯[J]. 日用化学工业, 2012,42(4): 285-287. [11] 靳敬敬，李芳，杨丽红. HZSM-5催化乙酸环己酯水解反应[J].石油学报(石油化工), 2014, 30(1): 169-174. [12] Stankiewicz A. Reactive separations for process intensification: An industrial perspective[J]. Chemical Engineering and Processing, 2003, 42(3): 137~144. [13] Khaledi R，Bishnoi P R. Amethod for modeling two-and three-phase reactive distillation columns[J]. Industrial and Engineering Chemistry Research, 2006, 45(17):6007-602. [14] Qiu T, Kuang J L, Lin H D, et al. Kinetic-Thermodynamic Analysis of the Reactive Distillation Process of the Cyclohexene Hydration Using the Zeolite Catalyst[J]. Chinese Journal of Chemical Engineering, 2011, 19(5): 808-814. [15] Katariya A, Freund H, Sundmacher K. Two-step reactive distillation proeessfor eyelohexanol produetion from cyelohexene[J]. Industrialand Engineering Chemistry Research. 2009, 48(21):9534-9545. [16] Steyer F, Freund H, Sundmaeher K. A novel reaetive distillation process for the indirect hydration of eyclohexene to cyelohexanol using a reactive entrainer[J]. Industrial and Engineering Chemistry Research. 2008, 47(23):9581-9587. [17] Schoenmakers H, Buhler W. Distillation column with external reactors - An alternative to the reaction column[J]. Chemie Ingenieur Technik, 1982, 54(2): 163. [18] Ye J C, Huang J L, Lin H D, et al. Evaluation of Reactive Distillation and Side Reactor Configuration for Direct Hydration of Cyclohexene to Cyclohexanol[J]. Industrial and Engineering Chemistry Research. 2014, 53:1461-1469. [19]Deng T, Zhao G, Liu Y, et al. Catalytic distillation for one-step cyclohexyl acetate production and cyclohexene-cyclohexane separation via esterification of cyclohexene with acetic acid over microfibrous-structured Nafion-SiO2/SS-fiber packings[J]. Chemical Engineering and Processing-Process Intensification. 2018, 131: 215-226.
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