1. 毕业设计(论文)的内容和要求
在锂离子电池中,将液态电解质替换为无机固态电解质, 可以大幅度提升电池的安全性和能量密度。
石榴石型结构的固态电解质(LLZO ) 因电化学稳定性好和电导率高等优点而倍受关注。
但是,固态电解质与锂金属负极之间的固固界面电阻大,阻碍了其进一步的发展。
2. 参考文献
(1) Cao, Y. L.; Li, M.; Lu, J.; Liu, J.; Amine, K. Bridging the Academic and Industrial Metrics for Next-Generation Practical Batteries. Nature Nanotech. 2019, 14, 200-207. (2) Du, M. J.; Liao, K. M.; Lu, Q.; Shao Z. P. Recent Advances in the Interface Engineering of Solid-State Li-Ion Batteries with Artificial Buffer Layers: Challenges, Materials, Construction, and Characterization. Energy Environ. Sci. 2019, 12, 1780-1804.(3) Sun, Y. M.; Liu, N.; Cui, Y. Promises and Challenges of Nanomaterials for Lithium-Based Rechargeable Batteries. Nature Energy 2016, 1, No. 16071.(4) Liao, K. M.; Wu, S. C.; Mu, X. W.; Lu, Q.; Han, M.; He, P.; Shao, Z. P.; Zhou, H. S. Developing a Water-Defendable and Dendrite-Free Lithium-Metal Anode Using a Simple and Promising GeCl4 Pretreatment Method. Adv. Mater. 2018, 30, No. 1705711.(5) Chi, S. S.; Liu, Y. C.; Song, W. L.; Fan, L. Z.; Zhang, Q. Prestoring Lithium into Stable 3D Nickel Foam Host as Dendrite-Free Lithium Metal Anode. Adv. Funct. Mater. 2017, 27, No. 1700348.
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