双核咪唑聚离子液体对二氧化碳的吸附及转化性能研究任务书

 2021-10-24 15:24:25

1. 毕业设计（论文）的内容和要求

1. 查阅、整理文献资料，加深对自己课题的理解，并撰写开题报告。

2. 要求学生对有机化学、无机与分析化学、仪器分析等学科复习，从而对以后双核咪唑聚离子液体对二氧化碳的吸附、转化性能研究打下基础。

3.采用无模板法制备双核咪唑聚离子液体，利用离子液体和交联剂进行共聚，即可制备双核咪唑聚离子液体。

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2. 参考文献

[1] 任勇源, 郭江娜, 孙哲, 等. 多孔聚离子液体的合成与应用[J]. 高分子通报，2018, (6): 21-31. [2] 钱文静, 郭江娜, 严锋. 功能化聚离子液体的设计合成及应用研究[J]. 高分子通报, 2015, (10): 94-104. [3] 骆静宜, 孙丽伟, 唐韶坤. 功能化聚合离子液体的合成及其在CO2吸附中的应用[J]. 高校化学工程学报, 2018, 32(06): 191-198. [4] Guo Z, Cai X, Xie J, et al. Hydroxyl-Exchanged Nanoporous Ionic Copolymer toward Low-Temperature Cycloaddition of Atmospheric Carbon Dioxide into Carbonates[J]. ACS Applied Materials Interfaces, 2016, 8(20): 12812-12821. [5] Ran H, Wang J, Abdeltawab A A, et al. Synthesis of polymeric ionic liquids material and application in CO2 adsorption[J]. Journal of Energy Chemistry, 2017, 26(5): 909-918. [6] 王晓晨, 刘安求, 董强, 等. 介孔聚离子液体的可控合成及在常压CO2环加成反应中应用[J]. 分子催化, 2019, 33(02): 86-94. [7] Tanmoy Biswas, Venkataramanan Mahalingam. Efficient CO2 fixation under ambient pressure using poly(ionic liquid)-based heterogeneous catalysts[J]. Sustainable Energy Fuels, 2019, 3(04): 935-941.[8] Song H, Wang Y, Xiao M, et al. Design of Novel Poly(ionic liquids) for the Conversion of CO2 to Cyclic Carbonates under Mild Conditions without Solvent[J]. ACS Sustainable Chemistry Engineering, 2019, 7(10): 9489-9497.[9] Qin L, Wang B, Zhang Y, et al. Anion exchange: a novel way of preparing hierarchical porous structure in poly(ionic liquid)s[J]. Chemical Communications, 2017, 53(26): 3785-3788.[10] Wang X, Zhang L, Guo Z, et al. Synergistic catalysis of one-pot cascade reactions by acidic and basic binary porous polymers[J]. Applied Surface Science, 2019, 478: 221-229.[11] Li D, Li J, Mao D, et al. Direct synthesis of sulfonic group tethered mesoporous poly(ionic liquid) for catalyzing deoximation reactions[J]. Materials Chemistry and Physics, 2017, 189: 118-126.[12] Guo Z, Jiang Q, Shi Y, et al. Tethering Dual Hydroxyls into Mesoporous Poly(ionic liquid)s for Chemical Fixation of CO2 at Ambient Conditions: A Combined Experimental and Theoretical Study[J]. ACS Catalysis, 2017, 7(10): 6770-6780. [13] 李春喜, 熊佳丽, 孟洪, 等. 从ILs到PILs聚合离子液体介孔材料的制备性质及结构调控方法[J]. 化工进展, 2016, 33(08): 1941-1950.[14] 李善建, 冯拉俊. 功能离子液体杂化固相纳米材料的制备及催化应用[J]. 化学进展, 2014, 26(10): 1633-1644.

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