基于螺吡喃的光响应吸附剂的制备与应用任务书

 2021-10-24 15:27:16

1. 毕业设计(论文)的内容和要求

选择性吸附和高效再生是评价吸附剂的两个重要关键点,具有固定孔结构的传统吸附剂难以同时实现。

本课题旨在针对传统吸附剂的不足,开发一类新型光响应吸附剂,通过吸附剂对光的刺激响应行为,实现对吸附剂孔径的调控,最终实现选择性吸附和高效再生。

毕业论文环节是大学学习的最后一个阶段,这一阶段需要我们将学习的基础理论和专业知识综合运用到课题的研究中,培养理论联系实际、严谨勤奋的工作态度和求实创新的科学作风,提高分析问题、解决问题和独立工作的能力。

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2. 参考文献

[1] Kang Y H, Liu X D, Yan N, Jiang Y, Liu X Q, Sun L B, Li J R. Fabrication of Isolated Metal-organic Polyhedra in Confined Cavities: Adsorbents/Catalysts with Unusual Dispersity and Activity [J]. J. Am. Chem. Soc., 2016, 138 (12): 6099-6102.[2] Jiang W-J, Yin Y, Liu X-Q, Yin X-Q, Shi Y-Q, Sun L-B. Fabrication of Supported Cuprous Sites at Low Temperatures: An Efficient Controllable Strategy Using Vapor-Induced Reduction [J]. J. Am. Chem. Soc., 2013, 135 (22): 8137-8140.[3] Jiang Y, Tan P, Cheng L, Shan S-F, Liu X-Q, Sun L-B. Selective Adsorption and Efficient Regeneration via Smart Adsorbents Possessing Thermo-Controlled Molecular Switches [J]. Phys. Chem. Chem. Phys., 2016, 18 (15): 9883-9887.[4] Li J-R, Yu J, Lu W, Sun L-B, Sculley J, Balbuena P B, Zhou H-C. Porous Materials with Pre-Designed Single-Molecule Traps for CO2 Selective Adsorption [J]. Nat. Commun., 2013, 4 (23): 1538-1543.[5] He, Y. et al. A Microporous Lanthanide-tricarboxylate Framework with the Potential for Purification of Natural Gas. Chem. Commun. 48, 10856-10858 (2012).[6] Rowsell, J.L.C., Eckert, J. hwiler D. Postsynthetic Functionalization of Mesoporous Silica [J]. Nanoscale, 2010, 2 (6): 887-892.[13] Jin Z, Xiao M, Bao Z, Wang P, Wang J. A General Approach to Mesoporous Metal Oxide Microspheres Loaded with Noble Metal Nanoparticles [J]. Angew. Chem., Int. Ed., 2012, 51 (26): 6406-6410.[14] Schth F. Non-Siliceous Mesostructured and Mesoporous Materials [J]. Chem. Mater., 2001, 13 (10): 3184-3195.[15] Gibson L. Mesosilica Materials and Organic Pollutant Adsorption: Part B Removal from Aqueous Solution [J]. Chem. Soc. Rev., 2014, 43 (15): 5173-5182.

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