1. 毕业设计(论文)的内容和要求
论文要求学生考察功能化多壁碳纳米管复合膜以及海藻酸钠膜的制膜条件,了解渗透汽化过程的原理,表征膜在渗透汽化过程中对乙醇/水体系的分离性能;通过实验,得到乙酸乙酯酯化反应的最佳条件;通过合理的实验设计,考察渗透汽化与酯化反应相耦合时对转化率的影响,并将实验结果与非耦合过程的结果进行比较。
通过上面的实验,培养学生综合设计实验能力、动手能力以及对实验获得的数据进行分析的能力,同时提高学生的外文翻译水平,为毕业生走上工作岗位或者继续深造提供良好的帮助。
2. 参考文献
[1] Liu H, Bai D, Bai H, et al. Constructing stereocomplex structures at the interface for remarkably accelerating matrix crystallization and enhancing the mechanical properties of poly (L-lactide)/multi-walled carbon nanotube nanocomposites[J]. Journal of Materials Chemistry A, 2015, 3(26): 13835-13847. [2] Yu-Kai Lin,Van-Huy Nguyen,Joseph Che-Chin Yu,Ching-Wei Lee,Yu-Heng Deng,Jeffrey C.S. Wu,Kevin C.W. Wu,Kuo-Lun Tung,Cheng-Liang Chen. Biodiesel production by pervaporation-assisted esterification and pre-esterification using graphene oxide/chitosan composite membranes,Journal of the Taiwan Institute of Chemical Engineers,2017:23-30 [3] Guan K , Liang F , Zhu H , et al. Incorporating graphene oxide into alginate polymer with cationic intermediate to strengthen membrane dehydration performance[J]. ACS Applied Materials 251:55.[10] Yang D, Tian D, Xue C, et al. Tuned fabrication of the aligned and opened CNT membrane with exceptionally high permeability and selectivity for bioalcohol recovery[J]. Nano letters, 2018, 18(10): 6150-6156. [11] Dudek G, Turczyn R, Konieczny K. Robust poly (vinyl alcohol) membranes containing chitosan/chitosan derivatives microparticles for pervaporative dehydration of ethanol[J]. Separation and Purification Technology, 2020, 234: 116094.[12] Zhu M, He B, Shi W, Feng Y, Ding J, Li J, Zeng F. Preparation and characterization of PSSA/PVA catalytic membrane for biodiesel production. FUEL 2010;89:2299.[13] Ma X H, Xu Z L, Liu Y, et al. Preparation and characterization of PFSAPVASiO2 /PVA/PAN difunctional hollow fiber composite membranes[J]. Journal of Membrane Science, 2010, 360(12):315-322.[14] Vishal S. Chandane,AJit P. Rathod,Kailas L. Wasewar. Enhancement of esterification conversion using pervaporation membrane reactor,ScienceDirect,2016:S47-S52[15] Rachipudi P S, Kariduraganavar M Y, Kittur A A, et al. Synthesis and characterization of sulfonated-poly(vinyl alcohol) membranes for the pervaporation dehydration of isopropanol[J]. Journal of Membrane Science, 2011, 383(1):224-234.[16] Caetano C S, Caiado M, Farinha J, et al. Esterification of free fatty acids over chitosan with sulfonic acid groups[J]. Chemical Engineering Journal, 2013, 230(16):567-572.[17] Shameli A, Ameri E. Synthesis of cross-linked PVA membranes embedded with multi-wall carbon nanotubes and their application to esterification of acetic acid with methanol[J]. Chemical Engineering Journal, 2017, 309: 381-396.[18] Han S , Li Y , Bai S , et al. Development of stable and active PVA-PSSA/SA-PVA catalytic composite membrane for esterification enhancement[J]. Journal of Applied Polymer Science, 2018:46514[19] Zhang W, Qing W, Ning C, et al. Enhancement of esterification conversion using novel composite catalytically active pervaporation membranes[J]. Journal of Membrane Science, 2014, 451(1):285-292.[20] Qing W, Chen J, Shi X, et al. Conversion enhancement for acetalization using a catalytically active membrane in a pervaporation membrane reactor[J]. Chemical Engineering Journal, 2016.
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