1. 毕业设计(论文)的内容和要求
1. 查阅、整理文献资料,加深对自己课题的理解,并撰写开题报告。
2. 要求学生对分离工程、无机与分析化学、仪器分析等学科复习,从而对实验测得谱图分析打下基础。
3. 研究目前主流环加成反应催化剂特点,分析CN掺杂改性的所需条件和方法,寻求不同的金属和非金属元素对CN材料进行改性,使离子能够成功掺杂进CN,并用XRD、FT-IR等表征手段进行表征。
2. 参考文献
[1] W.-H. Zhang, Pan-Pan He, et al. Graphene oxide grafted hydroxyl-functionalized ionic liquid: A highly efficient catalyst for cycloaddition of CO2 with epoxides[J]. Applied Catalysis A: General 509 (2016) 111117. [2] Liying Guo, Lili Deng, et al. Composite Ionic Liquids Immobilized on MCM-22 as Efcient Catalysts for the Cycloaddition Reaction with CO2 and Propylene Oxide [J]. Catal Lett (2017) 147:22902297.[3] Masoud Taheri, Mehran Ghiaci, et al. Cross-linked chitosan with a dicationic ionic liquid as a recyclable biopolymer-supported catalyst for cycloaddition of carbon dioxide with epoxides into cyclic carbonates[J]. New J. Chem, 2018, 42, 587597. [4] XianLei Shi, Yongju Chen, et al. Conversion of CO2 into Organic Carbonates over a Fiber-Supported Ionic Liquid Catalyst in Impellers of the Agitation System[J]. ACS Sustainable Chem. Eng. 2018, 6, 7119-7127. [5] J. Zhu, Shaoqing Wang, et al. A new and efficient method of graphene oxide immobilized with ionic liquids: Promoted catalytic activity for CO2 cycloaddition[J]. Materials Chemistry and Physics 208 (2018) 68-76.[6] Lina Han, Moon-Seok Park,et al. Incorporation of Metal Ions into Silica-Grafted Imidazolium Based Ionic Liquids to Efficiently Catalyze Cycloaddition Reactions of CO2 and Epoxides[J] . Catal Lett (2012) 142:259266.[7] Xiaohui Wu, Mengpan Wang et al. Carboxymethyl cellulose supported ionic liquid as a heterogeneous catalyst for the cycloaddition of CO2 to cyclic carbonate[J]. Applied Catalysis A: General 519 (2016) 146154.[8] Yu Lin Hu, Rong Xing. Highly Efcient and Convenient Supported Ionic LiquidTiCl5-DMIL@SiO2@Fe3O4-Catalyzed Cycloaddition of CO2 and Epoxides to Cyclic Carbonates[J]. Catal Lett (2017) 147:14531463.[9] Liying Guo, Xianchao Jin,et al. Immobilizing Polyether Imidazole Ionic Liquids on ZSM-5 Zeolite for the Catalytic Synthesis of Propylene Carbonate from Carbon Dioxide[J]. Molecules 2018, 23, 2710[10] Lingeswarran Muniandy, Farook Adam et al. Highly selective synthesis of cyclic carbonates via solvent free cycloaddition of CO2 and epoxides using ionic liquid grafted on rice husk derived MCM-41[J]. Inorganic Chemistry Communications 104 (2019) 17.[11]张景顺,任铁钢. 功能化吡唑类离子液体的合成及其催化CO_2环加成反应的研究[D].河南大学.2019.[12] 杨亮,刘伯运,等. 中空 Zn /Co ZIF 颗粒固载离子液体高效催化CO2环加成反应[A].广州化工.2019,47(15):56-58.[13] 梁丽亚,王建英,徐智策. 固载化酸性离子液体催化酯化反应研究[D].河北科技大学.2013.[14]李嘉伟,任颜卫,江焕峰. 金属有机框架材料在 CO2化学固定中的应用[A].化学进展. 2019,31( 10) : 1350 -1361.[15] 张亚平,矫庆.磁性负载型离子液体聚合物催化剂制备及其性能研究[J].北京理工大学.2015.
以上是毕业论文任务书,课题毕业论文、开题报告、外文翻译、程序设计、图纸设计等资料可联系客服协助查找。