全文总字数：4690字
1. 毕业设计（论文）的内容和要求
1. 查阅相关文献了解目前光响应吸附剂的研究现状以及应用前景，了解Π络合吸附剂在气体吸附方面的应用。
掌握课题相关背景，已有成果以及存在的问题，对论文的研究方向有较深入的认识。
2. 养成独立思考及动手做实验的能力，养成良好的科研习惯，增强分析问题解决问题的能力。
2. 实验内容和要求
1. 参照文献制备方法合成金属有机骨架材料MIL-101-NH2。
2. 对制备的MIL-101-NH2通过共价嫁接，引入光响应偶氮苯，之后采用浸渍法在偶氮苯载体上引入Π络合离子Cu(I)，最终制得光响应Π络合吸附剂。
同时探索络合离子负载量对吸附剂分离效果的影响。
3. 参考文献
(1) Khayyami, Aida; Philip, Anish; Karppinen, Maarit. Atomic/Molecular Layer Deposited Iron-Azobenzene Framework Thin Films for Stimuli-Induced Gas Molecule Capture/Release. Angew. Chem. Int. Ed. 2019, 58, 13400-13404.(2) Qian, Tianyue; Zhang, Huacheng; Li, Xingya; Hou, Jue; Zhao, Chen; Gu, Qinfen; Wang, Huanting. Efficient Gating of Ion Transport in Three-Dimensional Metal-Organic Framework Sub-Nanochannels with Confined Light-Responsive Azobenzene Molecules. Angew. Chem. Int. Ed. 2020, 59, 13051-13056.(3) Aguilera-Sigalat, Jordi; Bradshaw, Darren. A colloidal water-stable MOF as a broad-range fluorescent pH sensor via post-synthetic modification. Chem. Commun. 2014, 50, 4711-4713.(4) Garcia-Amoros, Jaume; Nonell, Santi; Velasco, Dolores. Photo-driven optical oscillators in the kHz range based on push-pull hydroxyazopyridines. Chem. Commun. 2011, 47, 4022-4024.(5) Allen, Corinne A.; Cohen, Seth M. Near-UV photo-induced modification in isoreticular metal-organic frameworks. J. Mater. Chem. 2012, 22, 10188-10194.(6) Liu, Chuanyao; Jiang, Yunzhe; Zhou, Chen; Caro, Juergen; Huang, Aisheng. Photo-switchable smart metal organic framework membranes with tunable and enhanced molecular sieving performance. J. Mater. Chem. A 2018, 6, 24949-24955.(7) He, Junpeng; Aggarwal, Kanchan; Katyal, Naman; He, Shichao; Chiang, Edward; Dunning, Samuel G.; Reynolds, Joseph E., III; Steiner, Alexander; Henkelman, Graeme; Que, Emily L.; Humphrey, Simon M. Reversible Solid-State Isomerism of Azobenzene-Loaded Large-Pore Isoreticular Mg-CUK-1. J. Am. Chem. Soc. 2020, 142, 6467-6471.(8) Meng, Xiangshi; Gui, Bo; Yuan, Daqiang; Zeller, Matthias; Wang, Cheng. Mechanized azobenzene-functionalized zirconium metal-organic framework for on-command cargo release. Sci. Adv. 2016, 2, (9) Yin, Yu; Wen, Zhihao; Shi, Lei; Zhang, Zhuangzhuang; Yang, Zhifeng; Xu, Chunli; Sun, Hongqi; Wang, Shaobin; Yuan, Aihua. Cuprous/Vanadium Sites on MIL-101 for Selective CO Adsorption from Gas Mixtures with Superior Stability. ACS Sustainable Chem. Eng. 2019, 7, 11284-11292.(10) Ahmed, Imteaz; Jhung, Sung Hwa. Adsorptive denitrogenation of model fuel with CuCl-loaded metal-organic frameworks (MOFs). Chemical Engineering Journal 2014, 251, 35-42.(11) Ahmed, Imteaz; Jhung, Sung Hwa. Remarkable improvement in adsorptive denitrogenation of model fossil fuels with CuCl/activated carbon, prepared under ambient condition. Chemical Engineering Journal 2015, 279, 327-334.(12) Le, Van Nhieu; Vo, The Ky; Lee, Jeong Hyeon; Kim, Jin Chul; Kim, Tea-Hoon; Oh, Kwang Hyun; Bae, Youn-Sang; Kwak, Sang Kyu; Kim, Jinsoo. A novel approach to prepare Cu(I)Zn@MIL-100(Fe) adsorbent with high CO adsorption capacity, CO/CO2 selectivity and stability via controlled host-guest redox reaction. Chemical Engineering Journal 2021, 404, (13) Xu, Xue-Yan; Chu, Chun; Fu, Huifen; Du, Xue-Dong; Wang, Peng; Zheng, Weiwei; Wang, Chong-Chen. Light-responsive UiO-66-NH2/Ag3PO4 MOF-nanoparticle composites for the capture and release of sulfamethoxazole. Chemical Engineering Journal 2018, 350, 436-444.(14) Vo, The Ky; Bae, Youn-Sang; Chang, Bong-Jun; Moon, Su-Young; Kim, Jeong-Hoon; Kim, Jinsoo. Highly CO selective Cu(I)-doped MIL-100(Fe) adsorbent with high CO/CO2 selectivity due to pi complexation: Effects of Cu(I) loading and activation temperature. Microporous Mesoporous Mater. 2019, 274, 17-24. (15) Chai, Yuchao; Han, Xue; Li, Weiyao; Liu, Shanshan; Yao, Sikai; Wang, Chong; Shi, Wei; da-Silva, Ivan; Manuel, Pascal; Cheng, Yongqiang; Daemen, Luke D.; Ramirez-Cuesta, Anibal J.; Tang, Chiu C.; Jiang, Ling; Yang, Sihai; Guan, Naijia; Li, Landong. Control of zeolite pore interior for chemoselective alkyne/olefin separations. Science 2020, 368, 1002-1003.
4. 毕业设计（论文）计划
2021.3.1-2021.3.10 查阅收集文献资料，了解课题背景，完成开题报告的撰写；为实验做准备工作。
2021.3.11-2021.3.31 合成光响应Π络合吸附剂，探索络合离子的最优负载量2021.4.1-2021.4.15 对引入偶氮苯和负载Cu(I)样品进行相应的表征测试，并且撰写中期自查表。
2021.4.16-2021.4.30 探索制备得到的材料Cu(I)@MIL-azo在吸附CO方面的应用，并进一步研究其响应性。
以上是毕业论文任务书，课题毕业论文、开题报告、外文翻译、程序设计、图纸设计等资料可联系客服协助查找。
