1. 毕业设计（论文）的内容和要求
有机硫化合物在有机合成、功能材料以及药物化学等研究领域都具有广泛用途, 探索高效的方法合成或利用含硫化合物是一个历久弥新的研究方向， 尤其是利用硫叶立德独特性质所发展的合成方法, 一直是有机硫化学的研究热点。
本课题通过设计并合成一系列含有硫醚及硫杂环的硫叶立德中间体，并考察其在有机合成中的活性。
2. 参考文献
[1] Mcgarrigle E M, Myers E L, Illa O, et al. Chalcogenides as organocatalysts. Chem Rev, 2007, 107: 58415883[2] Page P C B. Organosulfur Chemistry II. Berlin: Springer, 1999[3] Li A H, Dai L X. Asymmetric ylide reactions: Epoxidation, cyclopropanation, aziridination, olefination, and rearrangement. Chem Rev,1997, 97: 23412372[4] Aggarwal V K, Winn C L. Catalytic, asymmetric sulfur ylide-mediated epoxidation of carbonyl compounds: Scope, selectivity, and applications in synthesis. Acc Chem Res, 2004, 37: 611620[5] Lu L Q, Li T R, Wang Q, et al. Beyond sulfide-centric catalysis: Recent advances in the catalytic cyclization reactions of sulfur ylides.Chem Soc Rev, 2017, 46: 41354149[6] Bur S K, Padwa A. The Pummerer reaction: Methodology and strategy for the synthesis of heterocyclic compounds. Chem Rev, 2004, 35:24012432[7] Crivello J V. The discovery and development of onium salt cationic photoinitiators. J Polym Sci A Polym Chem, 1999, 37: 42414254[8] Dubrovskiy A V, Markina N A, Larock R C. Use of benzynes for the synthesis of heterocycles. Org Biomol Chem, 2013, 11: 191218[9] Shi J R, Li Y Y, Li Y. Aryne multifunctionalization with benzdiyne and benztriyne equivalents. Chem Soc Rev, 2017, 46: 17071719[10] Li Y M, Mck-Lichtenfeld C, Studer A. Sulfonium ylides by [3 2] cycloaddition of arynes with vinyl sulfides: Stereoselective synthesis of highly substituted alkenes. Angew Chem Int Ed, 2016, 55: 1443514438
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