1. 毕业设计(论文)的内容和要求
随着化石能源的使用,环境污染越来越严重,寻找并开发储存量大、分布广泛、符合绿色化学和可持续再生的代替资源是目前社会发展进程中的重大问题。
生物质是地球上储量最为丰富、价格便宜的可再生能源,可为原料制备生物燃料及工业化学品。
HMF是一种重要的平台化合物,可制备乙酰丙酸、2,5-二甲酰基呋喃及液态燃料等产品,还是合成精细化学品及功能材料的基础原料,具非常好的发展前景。
2. 参考文献
[1] Chheda J , Huber G , Dumesic J . Liquid-Phase Catalytic Processing of Biomass-Derived Oxygenated Hydrocarbons to Fuels and Chemicals[J]. Angewandte Chemie International Edition, 2007, 46(38):7164-7183.[2] Casanova O , Iborra S , Corma A . Biomass into Chemicals: Aerobic Oxidation of 5-Hydroxymethyl-2-furfural into 2,5-Furandicarboxylic Acid with Gold Nanoparticle Catalysts[J]. Chemsuschem, 2009, 2(12):1138-1144.[3] Moreau, Claude, Belgacem, Mohamed Naceur, Gandini, Alessandro. Recent Catalytic Advances in the Chemistry of Substituted Furans from Carbohydrates and in the Ensuing Polymers[J]. Topics in Catalysis, 2004, 27(1-4):11-30.[4] Alessandro Gandini, Armando J. D. Silvestre, Carlos Pascoal Neto,. The furan counterpart of poly(ethylene terephthalate): An alternative material based on renewable resources[J]. Journal of Polymer Science Part A Polymer Chemistry, 2008, 47(1):295-298.[5] Romn-Leshkov, Yuriy, Barrett, Christopher J, Liu, Zhen Y,. Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates[J]. Nature, 2004, 447(7147):982-985.[6] Binder, Joseph B, Raines, Ronald T. Simple Chemical Transformation of Lignocellulosic Biomass into Furans for Fuels and Chemicals[J]. Journal of the American Chemical Society, 131(5):1979-1985. [7] Liu Yang, George Tsilomelekis, Stavros Caratzoulas,. Mechanism of Bronsted Acid-Catalyzed Glucose Dehydration[J]. Chemsuschem, 2015, 8(8), 342-348.
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