1. 毕业设计（论文）的内容和要求
1. 毕业论文的要求有机硫化物广泛存在于许多天然产物、功能材料和合成药物中，因此碳硫键的形成引起人们极大的关注。
在有机硫化物合成方面，由钯或其他过渡金属催化的芳基卤化物和硫醇的Ulmann偶联反应是引入硫基团的有效方法之一，但是反应受到高负荷或超化学计量的金属催化剂或苛刻的反应条件的影响。
因此，有必要发展一种环境友好且高效的合成方法。
2. 参考文献
[1] Xiao B, Gong T J, Xu J, et al. Palladium-catalyzed intermolecular directed C H amidation of aromatic ketones[J]. Journal of the American Chemical Society, 2011, 133(5): 1466-1474. [2] Zhang, S.; Qian, P.; Zhang, M.; Hu, M.; Cheng, J. J. Org. Chem., 2010, 75 (19), 6732-6735.[3] Zhang, M.; Zhang, S.; Pan, C.; Chen, F. Synthetic Commun., 2012, 42 (19), 2844-2853.[4] Yan, G.; Borah, A. J.; Wang, L. Org. Biomol. Chem., 2014, 12 (47), 9557-9561.[5] Yu, Q.; Yang, Y.; Wan, J. P.; Liu, Y. J. Org. Chem., 2018, 83 (18), 11385-11391.[6] Guo S, He W, Xiang J, et al. Palladium-catalyzed thiolation of alkanes and ethers with arylsulfonyl hydrazides[J]. Chemical Communications, 2014, 50(62): 8578-8581. [7]Zhao X, Dimitrijevic E, Dong V M. Palladium-Catalyzed C-H Bond Functionalization withArylsulfonyl Chlorides[J]. J. Am. Chem. Soc., 2009, 131, 3466-3467.[8]Iwasaki M, Iyanaga M, Tsuchiya Y, et al. Palladium‐Catalyzed Direct Thiolation of Aryl C-H Bonds with Disulfides[J]. ChemistryA European Journal, 2014, 20(9): 2459-2462.[9] Saravanan, P.; Anbarasan, P. Org. Lett., 2014, 16 (3), 848-851.[10] Qiu, R. H.; Reddy, V. P.; Iwasaki, T.;Kambe,N.ThePalladium-Catalyzed Intermolecular C-HChalcogenation of Arenes[J]. J. Org.Chem., 2015, 80, 367-374[11]Xu Y, Liu P, Li S-L, et al. Palladium-Catalyzed ortho-Sulfonylation of 2-Aryloxypyridinesand Subsequent Formation of ortho-Sulfonylated Phenols[J]. J. Org. Chem., 2015, 80, 1269-1274.[12]Iwasaki M, Tsuchiya Y, Nakajima K, et al. Chelate-Assisted Direct Selenation of Aryl CH Bonds with Diselenides Catalyzed by Palladium[J]. Organic letters, 2014, 16(18): 4920-4923.[13]Iwasaki M, Kaneshika W, Tsuchiya Y, et al. Palladium-catalyzed peri-selective chalcogenation of naphthylamines with diaryl disulfides and diselenides via CH bond cleavage[J]. The Journal of organic chemistry, 2014, 79(23): 11330-11338.
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