1. 毕业设计（论文）的内容和要求
本课题拟通过邻香草醛和金属离子的组装合成锌-稀土配位簇合物并研究所得产物的荧光性能，为含稀土配合物的荧光性能的提高和调控提供参考。
2. 参考文献
[1] S. Huang et al, Luminescent 4f and d-4f polynuclear complexes and coordination polymers with flexible salen-type ligands, Coord. Chem. Rev., 2014, 273274, 63.[2] G. E. Kostakis et al, Four New Families of Polynuclear Zn-Ln Coordination Clusters. Synthetic, Topological, Magnetic, and Luminescent Aspects, Cryst. Growth Des. 2017, 17, 1524.[3] E. Colacio et al, Effect of the change of the ancillary carboxylate bridging ligand on the SMM and luminescence properties of a series of carboxylate-diphenoxido triply bridged dinuclear ZnLn and tetranuclear Zn2Ln2 complexes (Ln = Dy, Er), Dalton Trans., 2019, 48, 190.[4] B. Miroslaw et al, Heterometallic ZnIILnIIIZnII Schiff Base Complexes with Linear or Bent Conformation-Synthesis, Crystal Structures, Luminescent and Magnetic Characterization, Molecules, 2018, 23, 1761[5] R. A. Jones et al, Self-assembly of NIR luminescent 30-metaldrum-like and 12-metal rectangular df nanoclusters with long-chain Schiff base ligands, Chem. Commun., 2014, 50, 15569.[6] Wu Ke-Chen et al, Mixed d/f Complexes Zn(H2L)Ln(NO3)3 (Ln = Sm, Tb and Dy): Crystal Structure, Fluorescence and Thermal Stability, Chinese J. Struct. Chem., 2016, 35, 1383.[7] 张瑞莲，阴离子诱导的3d-4f 多核配合物的发光及催化性能研究，兰州大学，2018。
[8] 李峻峰等，稀土有机羧酸配合物体系发光材料，材料科学, 2018, 8，11。
[9] 郑姗姗，Salamo型3D-4f金属配合物的合成、晶体结构及荧光性质研究，兰州交通大学，2017。
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