1. 毕业设计（论文）的内容和要求
β-二酮二氟化硼配合物具有良好的刚性平面结构、较大的电荷分离能力、较大的摩尔吸光系数、较高的荧光量子产率以及对周围环境敏感等特点，同时与BODIPY不同是它具有较大的Stokes位移和较长的发射寿命，被认为是潜在的多功能材料并且已经被广泛的用于分子探针、非线性光学材料以及太阳能电池等领域，在过去的二十年得到了很大的开发并成为人们研究的热点。
针对不同领域对有机发光材料的应用需求，从功能分子的设计合成入手，通过化学结构修饰来研究分子结构与光学性质之间的构效关系，对于开发性能优良的发光材料尤为重要，也可为多功能荧光分子的设计研发提供理论依据和实验基础。
有机硼配合物由于发光强、光稳定性好，已经成为材料化学发展中不可或缺的一员。
2. 参考文献
[1] L. Bai, P. Sun, Y. Liu, H. Zhang, W. Hu, W. Zhang, Z. Liu, Q. Fan, L. Li, W. Huang, Novel aza-BODIPY based small molecular NIR-II fluorophores for in vivo imaging, Chem Commun 55(73) (2019) 10920-10923.[2] D.-H. Kim, A. DAlo, X.-K. Chen, A.D.S. Sandanayaka, D. Yao, L. Zhao, T. Komino, E. Zaborova, G. Canard, Y. Tsuchiya, E. Choi, J.W. Wu, F. Fages, J.-L. Brdas, J.-C. Ribierre, C. Adachi, High-efficiency electroluminescence and amplified spontaneous emission from a thermally activated delayed fluorescent near-infrared emitter, Nature Photonics 12(2) (2018) 98-104.[3] B. Bai, C. Yan, Y. Zhang, Z. Guo, W.H. Zhu, Dual-channel near-infrared fluorescent probe for real-time tracking of endogenous gamma-glutamyl transpeptidase activity, Chem Commun 54(87) (2018) 12393-12396.[4] L. Zhu, W. Xie, L. Zhao, Y. Zhang, Z. Chen, Tetraphenylethylene- and fluorene-functionalized near-infrared aza-BODIPY dyes for living cell imaging, RSC Advances 7(88) (2017) 55839-55845.[5] K. Tanaka, Y. Chujo, Recent progress of optical functional nanomaterials based on organoboron complexes with β-diketonate, ketoiminate and diiminate, NPG Asia Materials 7(11) (2015) 223.[6] S. Schutting, T. Jokic, M. Strobl, S.M. Borisov, D.d. Beer, I. Klimant, NIR optical carbon dioxide sensors based on highly photostable dihydroxy-aza-BODIPY dyes, Journal of Materials Chemistry C 3(21) (2015) 5474-5483.[7] M. Manley, Near-infrared spectroscopy and hyperspectral imaging: non-destructive analysis of biological materials, Chem Soc Rev 43(24) (2014) 8200-8214.[8] A. D'Alo, A. Felouat, V. Heresanu, A. Ranguis, D. Chaudanson, A. Karapetyan, M. Giorgi, F. Fages, Two-photon excited fluorescence of BF2 complexes of curcumin analogues: toward NIR-to-NIR fluorescent organic nanoparticles, J. Mater. Chem. C 2(26) (2014) 5208-5215.[9] A. DAlo, V. Heresanu, M. Giorgi, B. Le Guennic, D. Jacquemin, F. Fages, NIR Emission in Borondifluoride Complexes of 2′-Hydroxychalcone Derivatives Containing an Acetonaphthone Ring, The Journal of Physical Chemistry C 118(22) (2014) 11906-11918.[10] H. Xiang, J. Cheng, X. Ma, X. Zhou, J.J. Chruma, Near-infrared phosphorescence: materials and applications, Chem Soc Rev 42(14) (2013) 6128-6185.[11] A. D'Aleo, D. Gachet, V. Heresanu, M. Giorgi, F. Fages, Efficient NIR-light emission from solid-state complexes of boron difluoride with 2'-hydroxychalcone derivatives, Chemistry 18(40) (2012) 12764-12772.[12] E. Cogne-Laage, J.F. Allemand, O. Ruel, J.B. Baudin, V. Croquette, M. Blanchard-Desce, L. Jullien, Diaroyl(methanato)boron difluoride compounds as medium-sensitive two-photon fluorescent probes, Chemistry 10(6) (2004) 1445-1455.
以上是毕业论文任务书，课题毕业论文、开题报告、外文翻译、程序设计、图纸设计等资料可联系客服协助查找。
