马来腈基二硫醇镍配合物的合成、结构及性质研究任务书

 2022-02-07 20:44:35

全文总字数：2577字

1. 毕业设计（论文）的内容和要求

1.熟练马来腈基二硫醇离子化合物的合成2.熟练各种长晶体方法3.熟悉基本的表征手段，如PXRD、TG、IR、SCXRD4.掌握处理数据的软件，如origin、olex2

2. 实验内容和要求

1、掌握溶剂扩散法和溶剂挥发法等长单晶方法；2、掌握旋蒸仪、磁力搅拌器、烘箱等实验仪器的使用；3、熟悉X-射线单晶衍射测试、红外光谱分析、元素分析、粉末X射线衍射、热重分析、宽频介电阻抗、磁化率测试等分析方法；4、掌握实验数据处理软件的使用方法。

3. 参考文献

1.Jishkariani, Davit; Hall, C. Dennis; Oliferenko, Alexander A. , Cu(I)-Catalyzed Regioselective Synthesis of Pyrazolo[5,1-c]-1,2,4-triazoles, 2012, 77(13), 5813-5818.2. Ren, XM; Meng, QJ; Song, Y, Unusual magnetic properties of one-dimensional molecule-based magnets associated with a structural phase transition, 2002, 41(22), 5686-5692.3.Qian, Y;Shao, DS; Yao, WW; Wan, NK; Wang, XZ ;Ren, XM; Ion Conduction and Complicated Phase Transition Behaviors in an Organic Ion Plastic Crystal TBA2[Ni(mnt)2] (TBA = tetra(n-butyl)- ammonium and mnt2 = maleonitriledithiolate). J. Phys. Chem. C 2020, 124, 2072220729.4.He, JY; Chen, XR; Qian, Y; Crystal structures and dielectric properties of two salts of nickel-bis-1,2-dithiolene with noncentrosymmetric organic cations, 2018, 155, 42-49.5.Chang, T. H.; Hu, C. W.; Vittal, R.; Ho, K. C. Incorporation of Plastic Crystal and Transparent UV-Cured Polymeric Electrolyte in a Complementary Electrochromic Device. Solar Energy Mater. Solar Cells 2014, 126, 213-218.6.Li, B.; Kawakita, Y.; Ohira-Kawamura, S.; Sugahara, T.; Wang, H.; Wang, J.; Chen, Y.; Kawaguchi, S. I.; Kawaguchi, S.; Ohara, K.; Li, K.; Yu, D.; Mole, R.;Hattori, T.; Kikuchi, T.; Yano, S.-i.; Zhang, Z.; Zhang, Z.; Ren, W.; Lin, S.; Sakata, O.; Nakajima, K.; Zhang, Z. D. Colossal Barocaloric Effects in Plastic Crystals. Nature 2019, 567, 506-510.7.Lloveras, P.; Aznar, A.; Barrio, M.; Negrier, P.; Popescu, C.; Planes, A.; Maosa, L.; Stern-Taulats, E.; Avramenko, A.; Mathur, N. D.; Moya, X.; Tamarit, J.-LI. Colossal Barocaloric Effects Near Room Temperature in Plastic Crystals of Neopentylglycol. Nat. Commun. 2019, 10, 1803.8.Jin, L.; Nairn, K. M.; Forsyth, C. M.; Seeber, A. J.; MacFarlane, D. R.; Howlett, P. C.; Forsyth, M.; Pringle, J. M. Structure and Transport Properties of a Plastic Crystal Ion Conductor: Diethyl(methyl)(isobutyl)phosphonium Hexafluoro- phosphate. J. Am. Chem. Soc. 2012, 134, 9688-9697.9.Macfarlane, D. R.; Meakin, P.; Amini, N.; Forsyth, M. Structural Studies of Ambient Temperature Plastic Crystal Ion Conductors. J. Phys.: Condens. Matter. 2001, 13, 8257-8267.

4. 毕业设计（论文）计划

2020.11-2020.12 调研文献，熟悉操作过程，整理实验思路，拟定实验方案2021.1-2021.2 完成开题报告及外文翻译工作2021.3-2021.4 开展并完善实验过程，对合成产物进行表征2021.4-2021.5 对实验数据处理并分析，撰写毕业论文并修改，完成毕业答辩ppt

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