吡啶型卤键催化环状碳酸酯的合成任务书

 2021-10-23 20:17:07

1. 毕业设计（论文）的内容和要求

1.文献查阅从查阅文献着手，在中国期刊网，维普数据库，超星数字图书馆，美国化学学会(ACS)数据库，CA，SCI等检索资源上查阅有关碘取代的吡啶的合成方法、卤键的催化作用和二氧化碳固定的相关文献。

2．文献阅读及综述阅读与课题相关的文献，了解当下对二氧化碳利用基本情况、方法和国内外的研究动态，撰写文献综述。

3．明确实验任务，拟定实验方案根据所查阅文献的内容，确定实验内容及方案，拟定科学可行的研究计划。

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2. 参考文献

1.Yang, Shuaijun, Chu, Ming, Miao, Qian. Connecting Two Phenazines with a Four-Membered Ring: Synthesis, Properties and Applications of Cyclobuta[1,2-b:3,4-b\"]diphenazines[J]. Journal of Materials Chemistry C:10.1039.C7TC04092J.2.Heinen F , Engelage E , Dreger A , et al. Iodine(III) derivatives as halogen bonding organocatalysts[J]. Angewandte Chemie International Edition, 2018.3.Guha S , Kazi I , Nandy A , et al. Role of Lewis-Base-Coordinated Halogen(I) Intermediates in Organic Synthesis: The Journey from Unstable Intermediates to Versatile Reagents[J]. European Journal of Organic Chemistry, 2017.4.Bulfield D , Huber S M . Halogen Bonding in Organic Synthesis and Organocatalysis[J]. Chemistry - A European Journal, 2016.5.Gliese, Jan-Philipp, Jungbauer, Stefan H, Huber, Stefan M. A halogen-bonding-catalyzed Michael addition reaction[J]. Chemical Communications:10.1039.C7CC07175B.6.Alexander Dreger, Patrick Wonner, Elric Engelage,等. A halogen-bonding-catalysed Nazarov cyclisation reaction[J]. Chemical Communications, 2019, 55.7.Zhou H , Wang G X , Zhang W Z , et al. CO2 Adducts of Phosphorus Ylides: Highly Active Organocatalysts for Carbon Dioxide Transformation[J]. ACS Catalysis, 2015, 5( 11):150930105807006.8.Daniel V D H , Bozkus S , Klussmann M , et al. Reaction Mechanism of Iodine-Catalyzed Michael Additions[J]. The Journal of Organic Chemistry, 2017, 82(8):4037-4043.

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