1. 毕业设计(论文)的内容和要求
1.主要研究内容(1)以1-烷基-4-氨基-1,2,4-三唑( RATZ)做为阳离子,变换阴离子的种类如(Br-、NO3-、ClO4-),合成一系列三唑含能离子液体,并对其进行热稳定性分析,分析实验结果总结出实验规律(阴离子变换对1-烷基-4-氨基-1,2,4-三唑类含能离子热稳定的影响)。
(2)保持1-烷基-4-氨基-1,2,4-三唑含能离子液体中阴离子不变,变换烷基的种类(如:丁基,己基等),合成一系列三唑含能离子液体,并对其进行热稳定性分析,分析实验结果总结出实验规律(烷基种类的变换对1-烷基-4-氨基-1,2,4-三唑类含能离子热稳定的影响)2.研究要求(1)查阅有关书籍、手册和文献资料,了解目前含能离子液体合成及其热稳定性的研究现状,比较各种实验条件及实验方案下数据的可靠性。
(2)掌握实验室基本仪器操作。
2. 参考文献
[1] 何玲,陶国宏. 含能离子液体的功能化设计〔C〕. 中国化工学会. 2013中国化工学会年会论文集. 2013-11-14:355.[2]Singh R P, Verma R D, Shreeve J M, et al.Angew.Chem. Int. Ed. , 2006, 45:35843601.[3]Agrawal J P. Prog.Energy Combust. Sci.,1998, 24:1.[4]Drake G, Hawkins T, Mckay M, et al.Propellants, Explos. , Pyrotech. , 2003, 28: 174180.[5]Xue H, Arritt S W, Twamley B. Inorg. Chem. , 2004, 43:7972 7977.[6]Drake G, Kaplan G, Hall L, et al. J.Chem. Crystallogr. , 2007, 1: 1523.[7] 焦念明. 富B-H基离子液体推进剂的设计合成及性能研究〔D〕. 北京市:中国科学院过程工程研究所,2018.[8] 牟天成. 离子液体的热稳定性研究〔C〕. 2015年中国化工学会年会论文集.2015:150.[9] Y Cao,T Mu*, A comprehensive investigation on the thermal stability of 66 ionic liquids by thermogravimetric analysis, Ind Eng Chem Res, 2014, 53 (20), 86518664, Feature Article.[10] Y Chen, Y Cao, Y Shi, Z Xue, T Mu *, Quantitative Research on the Vaporization and Decomposition of [EMIM][Tf2N] by Thermogravimetric Analysis-Mass Spectrometry, Ind Eng Chem Res, 2012, 51(21), 7418-7427.[11] Z Xue, Y Zhang, X Zhou, Y Cao, T Mu*, Thermal stabilities and decomposition mechanism of amino- and hydroxyl-functionalized Ionic Liquids, Thermochimica Acta, 2014, 578, 59-67.[12] S Liu, Y Chen, Y Shi, H Sun*, H Xu, Z Zhou, T Mu*, Investigations on the thermal stability and decomposition mechanism of an aminefunctionalized ionic liquid by TGA, NMR, TG-MS experiments and DFT calculations, J Mol Liq, 2015.[13] X Sun, S Liu, A Khan, C Zhao, C Yan, T Mu*,Ionicity in acetate-based protic ionic liquids: evidences for both liquid and gaseous phases, New J Chem, 2014, 38 (8), 3449 3456.[14] G Li,T Mu*,in preparation.[15]Zhang W,Wang K,Li J,et al. Stabilization of the Pentazolate Anion in a Zeolitic Architec ture with Na20N60 and Na24N60 Nanocages[J] . Angewandte ChemieInternational Edition,2018,57:2592-2595.[16] :Li W,Wang K,Qi X,et al. Construction of a thermally stable and highly energetic metalorganic framework as leadfree primary explosives[J] . Crystal Growth Design.2018,18:1896-1902.[17]Jin Y,Wang B,Zhang W,et al. Synthesis and Properties of Triaminocyclopropenium Cat ion Based Ionic Liquids as Hypergolic Fluids[J] . Chem. Eur. J.,2018,24:4620-4627.[18] Wang W,Liu Y,Song S,et al. Accelerating the discovery of insensitive high ener gydensity materials by a materials genome approach[J] . Nature Communications,2018,9:2444.[19]Xue H,Shreeve J M.Ionic liquids with fluorine-containing cations[J] . Eur J Inorg Chem, 2005,( 13) : 2573 -2580.[20] Merrigan T L,Bates E D,Dorman S C,et al. New fluorous ionic liquids function as surfactants in conventional roomtemperature ionic liquids[J] . Chem Commun( Cambridge) , 2000,( 20) :2051 -2052.[21] Broeke J,Winter F,Deelman BJ, et al. A highly fluorous roomtemperature ionic liquid exhibiting fluorous biphasic behavior and its use in catalyst recycling[ J] .Org Lett, 2002, 4( 22) :3851 -3854.[22] Emnet C,Weber K M,Vidal J A,et al. Syntheses and properties of fluorous quaternary phosphonium salts that bear four ponytails; new candidates for phase transfer catalysts and ionic liquids[J] . Adv Synth Catal, 2006, 348:1625 -1634.[23] Caporiccio G,Flabbi L,Marchionni G,et al.The properties and applications of perfluoropolyether lubricants[ J] . J Synth Lubric, 1989, 6( 2) :133 -149[24] 温志勇,黄焰根. 新型含氟聚醚链修饰的咪唑离子液体的合成及其热稳定性[J]. 合成化学.2011,19(6): 694-698.
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